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Formation of Nanopatterned Polymer Blends in Photovoltaic Devices
Open accessAbstract
In this paper, we demonstrate a double nanoimprinting process that allows the formation of nanostructured polymer heterojunctions of composition and morphology that can be selected independently. We fabricated photovoltaic (PV) devices with extremely high densities (10(14)/mm(2)) of interpenetrating nanoscale columnar features in the active polymer blend layer. The smallest feature sizes are as small as 25 nm on a 50 nm pitch, which results in a spacing of heterojunctions at or below the exciton diffusion length. Photovoltaic devices based on double-imprinted poly((9,9-dioctylfluorene)-2,7-diyl-alt-[4,7-bis(3-hexylthien-5-yl)-2,1,3-benzothiadiazole]-2',2''-diyl) (F8TBT)/ poly(3-hexylthiophene) (P3HT) films are among the best polymer-polymer blend devices reported to date with a power conversion efficiency (PCE, eta(e)) of 1.9%.
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Cites
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
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Lin, Y., & Zhan, X. (2014) · Materials Horizons · doi:10.1039/c4mh00042k · Cited by 745
Polymer donor–polymer acceptor (all-polymer) solar cells
Facchetti, A. (2013) · Materials Today · doi:10.1016/j.mattod.2013.04.005 · Cited by 688
Light Harvesting for Organic Photovoltaics
Hedley, G. J., Ruseckas, A., & Samuel, I. D. W. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00215 · Cited by 580
Zang, Y., Li, C., Chueh, C., Williams, S. T., Jiang, W., Wang, Z., Yu, J., & Jen, A. K. ‐. (2014) · Advanced Materials · doi:10.1002/adma.201401992 · Cited by 422
Zhou, E., Cong, J., Wei, Q., Tajima, K., Yang, C., & Hashimoto, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201005408 · Cited by 419
Recent progress in organic photovoltaics: device architecture and optical design
Cao, W., & Xue, J. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00260a · Cited by 356
On the morphology of polymer‐based photovoltaics
Liu, F., Gu, Y., Jung, J. W., Jo, W. H., & Russell, T. P. (2012) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23063 · Cited by 323
Recent Advances in Wide‐Bandgap Photovoltaic Polymers
Cai, Y., Huo, L., & Sun, Y. (2017) · Advanced Materials · doi:10.1002/adma.201605437 · Cited by 313
Characterization of the morphology of solution-processed bulk heterojunction organic photovoltaics
Liu, F., Gu, Y., Shen, X., Ferdous, S., Wang, H.-W., & Russell, T. P. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.07.010 · Cited by 268
Metadata
- Authors
- He, X., Gao, F., Tu, G., Hasko, D., Hüttner, S., Steiner, U., Greenham, N. C., Friend, R. H., & Huck, W. T. S.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-03-03
- Volume
- 10
- Issue
- 4
- Pages
- 1302-1307
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2097505653
- Cited by
- 251
- References
- 1
- FWCI
- 25.17
- Type
- journal article
- Language
- en
- Open access
- green
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