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Carbon Nanotube/Manganese Oxide Ultrathin Film Electrodes for Electrochemical Capacitors
Abstract
Multiwall carbon nanotube (MWNT)/manganese oxide (MnO2) nanocomposite ultrathin film electrodes have been created via redox deposition of MnO2 on layer-by-layer (LbL)-assembled MWNT films. We demonstrate that these LbL-assembled MWNT (LbL-MWNT)/MnO2 thin films consist of a uniform coating of nanosized MnO2 on the MWNT network structure using SEM and TEM, which is a promising structure for electrochemical capacitor applications. LbL-MWNT/MnO2 electrodes yield a significantly higher volumetric capacitance of 246 F/cm3 with good capacity retention up to 1000 mV/s due to rapid transport of electrons and ions within the electrodes. The electrodes are generated with two simple aqueous deposition processes: the layer-by-layer assembly of MWNTs followed by redox deposition of MnO2 at ambient conditions, thus providing a straightforward approach to the fabrication of high-power and -energy electrochemical capacitors with precise control of electrode thickness at nanometer scales.
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Citations
Cited by
Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors
Lang, X., Hirata, A., Fujita, T., & Chen, M. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.13 · Cited by 2,109
Liu, J., Jiang, J., Cheng, C., Li, H., Zhang, J., Gong, H., & Fan, H. J. (2011) · Advanced Materials · doi:10.1002/adma.201100058 · Cited by 1,311
Yu, G., Hu, L., Vosgueritchian, M., Wang, H., Xie, X., McDonough, J. R., Cui, X., Cui, Y., & Bao, Z. (2011) · Nano Letters · doi:10.1021/nl2013828 · Cited by 1,239
Large‐Scale Exfoliation of Inorganic Layered Compounds in Aqueous Surfactant Solutions
Smith, R. J., King, P. J., Lotya, M., Wirtz, C., Khan, U., De, S., O'Neill, A., Duesberg, G. S., Grunlan, J. C., Moriarty, G., et al. (2011) · Advanced Materials · doi:10.1002/adma.201102584 · Cited by 1,161
From coconut shell to porous graphene-like nanosheets for high-power supercapacitors
Sun, L., Tian, C., Li, M., Meng, X., Wang, L., Wang, R., Yin, J., & Fu, H. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta10897j · Cited by 961
Metadata
- Authors
- Lee, S. W., Kim, J., Chen, S., Hammond, P. T., & Shao-Horn, Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-06-16
- Volume
- 4
- Issue
- 7
- Pages
- 3889-3896
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1969917601
- Cited by
- 728
- References
- 0
- FWCI
- 24.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, S. W., Kim, J., Chen, S., Hammond, P. T., & Shao-Horn, Y. (2010). Carbon Nanotube/Manganese Oxide Ultrathin Film Electrodes for Electrochemical Capacitors. ACS Nano. https://doi.org/10.1021/nn100681d
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