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High-Efficiency Dye-Sensitized Solar Cells: The Influence of Lithium Ions on Exciton Dissociation, Charge Recombination, and Surface States
Abstract
We present a time-saving staining protocol based upon the low-toxicity and nonvolatile solvent dimethyl sulfoxide for a high-efficiency dye-sensitized solar cell, which is very critical for the roll-to-roll flexible cell production. Power conversion efficiencies of 11.7-12.1% were achieved under AM1.5G simulated sunlights. The intrinsic roles of lithium cations on efficiency enhancement were scrutinized by measuring transient absorption and electrical impedance spectroscopies. Our studies have revealed that lithium ions can enhance exciton dissociation at the energy-offset dye/titania interface effectively. Charge collection is not found to be a crucial current loss channel in our high-efficiency dye-sensitized solar cell.
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Cites
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
O'Regan, B., & Grätzel, M. (1991) · Nature · doi:10.1038/353737a0 · Cited by 28,599
Density-Functional Theory for Time-Dependent Systems
Runge, E., & Gross, E. K. U. (1984) · Physical Review Letters · doi:10.1103/physrevlett.52.997 · Cited by 8,914
Cited by
Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy
Fabregat-Santiago, F., Garcia-Belmonte, G., Mora-Seró, I., & Bisquert, J. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp02249g · Cited by 1,206
Meso-Substituted Porphyrins for Dye-Sensitized Solar Cells
Urbani, M., Grätzel, M., Nazeeruddin, M. K., & Torres, T. (2014) · Chemical Reviews · doi:10.1021/cr5001964 · Cited by 940
High-efficiency dye-sensitized solar cells with ferrocene-based electrolytes
Daeneke, T., Kwon, T.-H., Holmes, A. B., Duffy, N. W., Bach, U., & Spiccia, L. (2011) · Nature Chemistry · doi:10.1038/nchem.966 · Cited by 586
Dye-sensitized solar cells strike back
Muñoz-García, A. B., Benesperi, I., Boschloo, G., Concepcion, J. J., Delcamp, J. H., Gibson, E. A., Meyer, G. J., Pavone, M., Pettersson, H., Hagfeldt, A., et al. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01336f · Cited by 544
Yella, A., Mai, C., Zakeeruddin, S. M., Chang, S., Hsieh, C., Yeh, C., & Grätzel, M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309343 · Cited by 482
Metadata
- Authors
- Yu, Q., Wang, Y., Yi, Z., Zu, N., Zhang, J., Zhang, M., & Wang, P.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-05
- Volume
- 4
- Issue
- 10
- Pages
- 6032-6038
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2006328333
- Cited by
- 555
- References
- 2
- FWCI
- 28.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, Q., Wang, Y., Yi, Z., Zu, N., Zhang, J., Zhang, M., & Wang, P. (2010). High-Efficiency Dye-Sensitized Solar Cells: The Influence of Lithium Ions on Exciton Dissociation, Charge Recombination, and Surface States. ACS Nano. https://doi.org/10.1021/nn101384e
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