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Soluble P3HT-Grafted Graphene for Efficient Bilayer−Heterojunction Photovoltaic Devices
Abstract
CH(2)OH-terminated regioregular poly(3-hexylthiophene) (P3HT) was chemically grafted onto carboxylic groups of graphene oxide (GO) via esterification reaction. The resultant P3HT-grafted GO sheets (G-P3HT) are soluble in common organic solvents, facilitating the structure/property characterization and the device fabrication by solution processing. The covalent linkage and the strong electronic interaction between the P3HT and graphene moieties in G-P3HT were confirmed by spectroscopic analyses and electrochemical measurements. A bilayer photovoltaic device based on the solution-cast G-P3HT/C(60) heterostructures showed a 200% increase of the power conversion efficiency (η = 0.61%) with respect to the P3HT/C(60) counterpart under AM 1.5 illumination (100 mW/cm(2)).
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Metadata
- Authors
- Yu, D., Yang, Y., Durstock, M., Baek, J.-B., & Dai, L.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-10
- Volume
- 4
- Issue
- 10
- Pages
- 5633-5640
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2157037094
- Cited by
- 470
- References
- 26
- FWCI
- 24.17
- Type
- journal article
- Language
- en
- Open access
- closed
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