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Au@Ag Core−Shell Nanocubes with Finely Tuned and Well-Controlled Sizes, Shell Thicknesses, and Optical Properties
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This paper describes a facile method for generating Au@Ag core-shell nanocubes with edge lengths controllable in the range of 13.4-50 nm. The synthesis involved the use of single-crystal, spherical Au nanocrystals of 11 nm in size as the seeds in an aqueous system, with ascorbic acid serving as the reductant and cetyltrimethylammonium chloride (CTAC) as the capping agent. The thickness of the Ag shells could be finely tuned from 1.2 to 20 nm by varying the ratio of AgNO(3) precursor to Au seeds. We also investigated the growth mechanism by examining the effects of seeds (capped by CTAC or cetyltrimethylammonium bromide(CTAB)) and capping agent (CTAC vs CTAB) on both size and shape of the resultant core-shell nanocrystals. Our results clearly indicate that CTAC worked much better than CTAB as a capping agent in both the syntheses of Au seeds and Au@Ag core-shell nanocubes. We further studied the localized surface plasmon resonance properties of the Au@Ag nanocubes as a function of the Ag shell thickness. By comparing with the extinction spectra obtained from theoretical calculations, we derived a critical value of ca. 3 nm for the shell thickness at which the plasmon excitation of the Au cores would be completely screened by the Ag shells. Moreover, these Au@Ag core-shell nanocubes could be converted into Au-based hollow nanostructures containing the original Au seeds in the interiors through a galvanic replacement reaction.
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Cites
Kelly, K. L., Coronado, E., Zhao, L. L., & Schatz, G. C. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp026731y · Cited by 10,594
Anisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications
Murphy, C. J., Sau, T. K., Gole, A. M., Orendorff, C. J., Gao, J., Gou, L., Hunyadi, S. E., & Li, T. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0516846 · Cited by 3,085
Nanoparticles with Raman Spectroscopic Fingerprints for DNA and RNA Detection
Cao, Y. C., Jin, R., & Mirkin, C. A. (2002) · Science · doi:10.1126/science.297.5586.1536 · Cited by 2,971
Gold Nanoparticles in Biology: Beyond Toxicity to Cellular Imaging
Murphy, C. J., Gole, A. M., Stone, J. W., Sisco, P. N., Alkilany, A. M., Goldsmith, E. C., & Baxter, S. C. (2008) · Accounts of Chemical Research · doi:10.1021/ar800035u · Cited by 1,807
Controlling anisotropic nanoparticle growth through plasmon excitation
Jin, R., Charles Cao, Y., Hao, E., Métraux, G. S., Schatz, G. C., & Mirkin, C. A. (2003) · Nature · doi:10.1038/nature02020 · Cited by 1,674
Shape‐Controlled Synthesis of Metal Nanostructures: The Case of Silver
Wiley, B., Sun, Y., Mayers, B., & Xia, Y. (2005) · Chemistry – A European Journal · doi:10.1002/chem.200400927 · Cited by 1,643
Self-citationWiley, B. J., Im, S. H., Li, Z.-Y., McLellan, J., Siekkinen, A., & Xia, Y. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0608628 · Cited by 1,159
Self-citationA Text-Book of Physical Chemistry
(1936) · Nature · doi:10.1038/138864b0 · Cited by 1,146
Fan, F.-R., Liu, D.-Y., Wu, Y.-F., Duan, S., Xie, Z.-X., Jiang, Z.-Y., & Tian, Z.-Q. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801566d · Cited by 783
Self-citationPolyhedral Silver Nanocrystals with Distinct Scattering Signatures
Tao, A., Sinsermsuksakul, P., & Yang, P. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200601277 · Cited by 758
Anisotropic Etching of Silver Nanoparticles for Plasmonic Structures Capable of Single-Particle SERS
Mulvihill, M. J., Ling, X. Y., Henzie, J., & Yang, P. (2010) · Journal of the American Chemical Society · doi:10.1021/ja906954f · Cited by 645
Gold Nanocages: Engineering Their Structure for Biomedical Applications
Chen, J., Wiley, B., Li, Z. ‐., Campbell, D., Saeki, F., Cang, H., Au, L., Lee, J., Li, X., & Xia, Y. (2005) · Advanced Materials · doi:10.1002/adma.200500833 · Cited by 590
Self-citationChemical sensing and imaging with metallic nanorods
Murphy, C. J., Gole, A. M., Hunyadi, S. E., Stone, J. W., Sisco, P. N., Alkilany, A., Kinard, B. E., & Hankins, P. (2008) · Chem. Commun. · doi:10.1039/b711069c · Cited by 564
Controlling the Shapes of Silver Nanocrystals with Different Capping Agents
Zeng, J., Zheng, Y., Rycenga, M., Tao, J., Li, Z.-Y., Zhang, Q., Zhu, Y., & Xia, Y. (2010) · Journal of the American Chemical Society · doi:10.1021/ja103655f · Cited by 469
Self-citationSynthesis and Optical Characterization of Au/Ag Core/Shell Nanorods
Liu, & Guyot-Sionnest, P. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp037644o · Cited by 448
A facile synthesis of monodisperse Au nanoparticles and their catalysis of CO oxidation
Peng, S., Lee, Y., Wang, C., Yin, H., Dai, S., & Sun, S. (2008) · Nano Research · doi:10.1007/s12274-008-8026-3 · Cited by 439
Right Bipyramids of Silver: A New Shape Derived from Single Twinned Seeds
Wiley, B. J., Xiong, Y., Li, Z.-Y., Yin, Y., & Xia, Y. (2006) · Nano Letters · doi:10.1021/nl060069q · Cited by 409
Self-citationSynthesis and Optical Properties of Gold Nanodecahedra with Size Control
Sánchez‐Iglesias, A., Pastoriza‐Santos, I., Pérez‐Juste, J., Rodríguez‐González, B., García de Abajo, F. J., & Liz‐Marzán, L. M. (2006) · Advanced Materials · doi:10.1002/adma.200600475 · Cited by 379
Siekkinen, A. R., McLellan, J. M., Chen, J., & Xia, Y. (2006) · Chemical Physics Letters · doi:10.1016/j.cplett.2006.10.095 · Cited by 361
Self-citationNiu, W., Zheng, S., Wang, D., Liu, X., Li, H., Han, S., Chen, J., Tang, Z., & Xu, G. (2009) · Journal of the American Chemical Society · doi:10.1021/ja804115r · Cited by 358
A textbook of physical chemistry
Adamson, A. W. (1973) · Cited by 343
Integration of photonic and silver nanowire plasmonic waveguides
Pyayt, A. L., Wiley, B. J., Younan Xia, A., Chen, A., & Dalton, L. R. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.281 · Cited by 341
Controlling the Edge Length of Gold Nanoprisms via a Seed‐Mediated Approach
Millstone, J. E., Métraux, G. S., & Mirkin, C. A. (2006) · Advanced Functional Materials · doi:10.1002/adfm.200600066 · Cited by 303
A Comparative Study of Galvanic Replacement Reactions Involving Ag Nanocubes and AuCl2− or AuCl4−
Au, L., Lu, X., & Xia, Y. (2008) · Advanced Materials · doi:10.1002/adma.200800255 · Cited by 252
Self-citationSeo, D., Yoo, C. I., Chung, I. S., Park, S. M., Ryu, S., & Song, H. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp7109498 · Cited by 248
Plasmon‐Driven Synthesis of Triangular Core–Shell Nanoprisms from Gold Seeds
Xue, C., Millstone, J. E., Li, S., & Mirkin, C. A. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200703185 · Cited by 219
Tsuji, M., Miyamae, N., Lim, S., Kimura, K., Zhang, X., Hikino, S., & Nishio, M. (2006) · Crystal Growth & Design · doi:10.1021/cg060103e · Cited by 206
Bimetallic silver–gold nanowires: fabrication and use in surface-enhanced Raman scattering
Hunyadi, S. E., & Murphy, C. J. (2006) · J. Mater. Chem. · doi:10.1039/b607116c · Cited by 186
Synthesis and Characterization of Noble‐Metal Nanostructures Containing Gold Nanorods in the Center
Cho, E. C., Camargo, P. H. C., & Xia, Y. (2010) · Advanced Materials · doi:10.1002/adma.200903097 · Cited by 172
Self-citationGonzalez, C., Liu, Y., & Scaiano, J. C. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902061v · Cited by 158
Zhang, J., Liu, H., Wang, Z., & Ming, N. (2007) · Advanced Functional Materials · doi:10.1002/adfm.200700497 · Cited by 142
Tsuji, M., Matsuo, R., Jiang, P., Miyamae, N., Ueyama, D., Nishio, M., Hikino, S., Kumagae, H., Kamarudin, K. S. N., & Tang, X.-L. (2008) · Crystal Growth & Design · doi:10.1021/cg800162t · Cited by 123
Photochemical Formation of Silver Nanodecahedra: Structural Selection by the Excitation Wavelength
Zheng, X., Zhao, X., Guo, D., Tang, B., Xu, S., Zhao, B., Xu, W., & Lombardi, J. R. (2009) · Langmuir · doi:10.1021/la803814j · Cited by 113
Directed Surface Overgrowth and Morphology Control of Polyhedral Gold Nanocrystals
Seo, D., Yoo, C. I., Park, J. C., Park, S. M., Ryu, S., & Song, H. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200704094 · Cited by 108
Core−Shell Triangular Bifrustums
Yoo, H., Millstone, J. E., Li, S., Jang, J., Wei, W., Wu, J., Schatz, G. C., & Mirkin, C. A. (2009) · Nano Letters · doi:10.1021/nl901513g · Cited by 84
Tsuji, M., Maeda, Y., Hikino, S., Kumagae, H., Matsunaga, M., Tang, X., Matsuo, R., Ogino, M., & Jiang, P. (2009) · Crystal Growth & Design · doi:10.1021/cg900563y · Cited by 52
Yavuz, M. S., Li, W., & Xia, Y. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200901440 · Cited by 51
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Yang, X., Yang, M., Pang, B., Vara, M., & Xia, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00193 · Cited by 1,162
Self-citationTemplated Techniques for the Synthesis and Assembly of Plasmonic Nanostructures
Jones, M. R., Osberg, K. D., Macfarlane, R. J., Langille, M. R., & Mirkin, C. A. (2011) · Chemical Reviews · doi:10.1021/cr1004452 · Cited by 1,159
Seed‐Mediated Growth of Colloidal Metal Nanocrystals
Xia, Y., Gilroy, K. D., Peng, H., & Xia, X. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201604731 · Cited by 800
Self-citationHang, Y., Wang, A., & Wu, N. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00793f · Cited by 473
Ha, M., Kim, J.-H., You, M., Li, Q., Fan, C., & Nam, J.-M. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00234 · Cited by 466
Metadata
- Authors
- Ma, Y., Li, W., Cho, E. C., Li, Z., Yu, T., Zeng, J., Xie, Z., & Xia, Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-22
- Volume
- 4
- Issue
- 11
- Pages
- 6725-6734
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2082994362
- Cited by
- 584
- References
- 37
- FWCI
- 14.15
- Type
- journal article
- Language
- en
- Open access
- green
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