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Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing
Abstract
Anticorrosion and antioxidation surface treatments such as paint or anodization are a foundational component in nearly all industries. Graphene, a single-atom-thick sheet of carbon with impressive impermeability to gases, seems to hold promise as an effective anticorrosion barrier, and recent work supports this hope. We perform a complete study of the short- and long-term performance of graphene coatings for Cu and Si substrates. Our work reveals that although graphene indeed offers effective short-term oxidation protection, over long time scales it promotes more extensive wet corrosion than that seen for an initially bare, unprotected Cu surface. This surprising result has important implications for future scientific studies and industrial applications. In addition to informing any future work on graphene as a protective coating, the results presented here have implications for graphene's performance in a wide range of applications.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Cited by
Atomically Thin Boron Nitride: Unique Properties and Applications
Li, L. H., & Chen, Y. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201504606 · Cited by 499
A brief review of corrosion protective films and coatings based on graphene and graphene oxide
Ding, R., Li, W., Wang, X., Gui, T., Li, B., Han, P., Tian, H., Liu, A., Wang, X., Liu, X., et al. (2018) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2018.06.133 · Cited by 359
Multifunctionality and Mechanical Actuation of 2D Materials for Skin‐Mimicking Capabilities
Chang, T., Li, K., Yang, H., & Chen, P. (2018) · Advanced Materials · doi:10.1002/adma.201802418 · Cited by 94
Metadata
- Authors
- Schriver, M., Regan, W., Gannett, W. J., Zaniewski, A. M., Crommie, M. F., & Zettl, A.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-11
- Volume
- 7
- Issue
- 7
- Pages
- 5763-5768
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2170776011
- Cited by
- 724
- References
- 1
- FWCI
- 20.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schriver, M., Regan, W., Gannett, W. J., Zaniewski, A. M., Crommie, M. F., & Zettl, A. (2013). Graphene as a Long-Term Metal Oxidation Barrier: Worse Than Nothing. ACS Nano. https://doi.org/10.1021/nn4014356
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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