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Ultrafast Saturable Absorption of Two-Dimensional MoS2 Nanosheets
Abstract
Employing high-yield production of layered materials by liquid-phase exfoliation, molybdenum disulfide (MoS2) dispersions with large populations of single and few layers were prepared. Electron microscopy verified the high quality of the two-dimensional MoS2 nanostructures. Atomic force microscopy analysis revealed that ~39% of the MoS2 flakes had thicknesses of less than 5 nm. Linewidth and frequency difference of the E(1)2g and A1g Raman modes confirmed the effective reduction of flake thicknesses from the bulk MoS2 to the dispersions. Ultrafast nonlinear optical (NLO) properties were investigated using an open-aperture Z-scan technique. All experiments were performed using 100 fs pulses at 800 nm from a mode-locked Ti:sapphire laser. The MoS2 nanosheets exhibited significant saturable absorption (SA) for the femtosecond pulses, resulting in the third-order NLO susceptibility Imχ((3)) ~ 10(-15) esu, figure of merit ~10(-15) esu cm, and free-carrier absorption cross section ~10(-17) cm(2). Induced free carrier density and the relaxation time were estimated to be ~10(16) cm(-3) and ~30 fs, respectively. At the same excitation condition, the MoS2 dispersions show better SA response than the graphene dispersions.
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Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
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Cited by
Du, J., Wang, Q., Jiang, G., Xu, C., Zhao, C., Xiang, Y., Chen, Y., Wen, S., & Zhang, H. (2014) · Scientific Reports · doi:10.1038/srep06346 · Cited by 465
Self-citationHe, Z., & Que, W. (2016) · Applied Materials Today · doi:10.1016/j.apmt.2016.02.001 · Cited by 438
Optical Limiting and Theoretical Modelling of Layered Transition Metal Dichalcogenide Nanosheets
Dong, N., Li, Y., Feng, Y., Zhang, S., Zhang, X., Chang, C., Fan, J., Zhang, L., & Wang, J. (2015) · Scientific Reports · doi:10.1038/srep14646 · Cited by 321
Self-citationUltrafast fiber lasers mode-locked by two-dimensional materials: review and prospect
Jiang, T., Yin, K., Wang, C., You, J., Ouyang, H., Miao, R., Zhang, C., Wei, K., Li, H., Chen, H., et al. (2020) · Photonics Research · doi:10.1364/prj.8.000078 · Cited by 319
Self-citationEmerging 2D materials beyond graphene for ultrashort pulse generation in fiber lasers
He, J., Tao, L., Zhang, H., Zhou, B., & Li, J. (2019) · Nanoscale · doi:10.1039/c8nr09368g · Cited by 282
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Metadata
- Authors
- Wang, K., Wang, J., Fan, J., Lotya, M., O’Neill, A., Fox, D., Feng, Y., Zhang, X., Jiang, B., Zhao, Q., Zhang, H., Coleman, J. N., Zhang, L., & Blau, W. J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-07
- Volume
- 7
- Issue
- 10
- Pages
- 9260-9267
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2321770094
- Cited by
- 1,026
- References
- 2
- FWCI
- 35.37
- Type
- journal article
- Language
- en
- Open access
- closed
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