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Porous Spinel ZnxCo3–xO4 Hollow Polyhedra Templated for High-Rate Lithium-Ion Batteries
Abstract
Nanostructured metal oxides with both anisotropic texture and hollow structures have attracted considerable attention with respect to improved electrochemical energy storage and enhanced catalytic activity. While synthetic strategies for the preparation of binary metal oxide hollow structures are well-established, the rational design and fabrication of complex ternary metal oxide with nonspherical hollow features is still a challenge. Herein, we report a simple and scalable strategy to fabricate highly symmetric porous ternary ZnxCo3-xO4 hollow polyhedra composed of nanosized building blocks, which involves a morphology-inherited and thermolysis-induced transformation of heterobimetallic zeolitic imidazolate frameworks. When tested as anode materials for lithium-ion batteries, these hollow polyhedra have exhibited excellent electrochemical performance with high reversible capacity, excellent cycling stability, and good rate capability.
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Cited by
Huang, Z.-F., Song, J., Li, K., Tahir, M., Wang, Y.-T., Pan, L., Wang, L., Zhang, X., & Zou, J.-J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11986 · Cited by 749
Conversion Reaction‐Based Oxide Nanomaterials for Lithium Ion Battery Anodes
Yu, S., Lee, S. H., Lee, D. J., Sung, Y., & Hyeon, T. (2016) · Small · doi:10.1002/smll.201502299 · Cited by 499
Metadata
- Authors
- Wu, R., Qian, X., Zhou, K., Wei, J., Lou, J., & Ajayan, P. M.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-22
- Volume
- 8
- Issue
- 6
- Pages
- 6297-6303
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1966788841
- Cited by
- 421
- References
- 0
- FWCI
- 33.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, R., Qian, X., Zhou, K., Wei, J., Lou, J., & Ajayan, P. M. (2014). Porous Spinel ZnxCo3–xO4 Hollow Polyhedra Templated for High-Rate Lithium-Ion Batteries. ACS Nano. https://doi.org/10.1021/nn501783n
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