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Extraordinary Photoluminescence and Strong Temperature/Angle-Dependent Raman Responses in Few-Layer Phosphorene
Open accessAbstract
Phosphorene is a new family member of two-dimensional materials. We observed strong and highly layer-dependent photoluminescence in few-layer phosphorene (two to five layers). The results confirmed the theoretical prediction that few-layer phosphorene has a direct and layer-sensitive band gap. We also demonstrated that few-layer phosphorene is more sensitive to temperature modulation than graphene and MoS2 in Raman scattering. The anisotropic Raman response in few-layer phosphorene has enabled us to use an optical method to quickly determine the crystalline orientation without tunneling electron microscopy or scanning tunneling microscopy. Our results provide much needed experimental information about the band structures and exciton nature in few-layer phosphorene.
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Self-citationGeim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
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Cited by
Polaritons in layered two-dimensional materials
Low, T., Chaves, A., Caldwell, J. D., Kumar, A., Fang, N. X., Avouris, P., Heinz, T. F., Guinea, F., Martin-Moreno, L., & Koppens, F. (2017) · Nature Materials · doi:10.1038/nmat4792 · Cited by 1,317
Zeng, M., Xiao, Y., Liu, J., Yang, K., & Fu, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00633 · Cited by 574
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
Li, B., Lai, C., Zeng, G., Huang, D., Qin, L., Zhang, M., Cheng, M., Liu, X., Yi, H., Zhou, C., et al. (2019) · Small · doi:10.1002/smll.201804565 · Cited by 367
Black phosphorus and its isoelectronic materials
Xia, F., Wang, H., Hwang, J. C. M., Neto, A. H. C., & Yang, L. (2019) · Nature Reviews Physics · doi:10.1038/s42254-019-0043-5 · Cited by 322
Metadata
- Authors
- Zhang, S., Yang, J., Xu, R., Wang, F., Li, W., Ghufran, M., Zhang, Y.-W., Yu, Z., Zhang, G., Qin, Q., & Lu, Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-08
- Volume
- 8
- Issue
- 9
- Pages
- 9590-9596
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2080516950
- Cited by
- 688
- References
- 5
- FWCI
- 40.65
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhang, S., Yang, J., Xu, R., Wang, F., Li, W., Ghufran, M., Zhang, Y.-W., Yu, Z., Zhang, G., Qin, Q., & Lu, Y. (2014). Extraordinary Photoluminescence and Strong Temperature/Angle-Dependent Raman Responses in Few-Layer Phosphorene. ACS Nano. https://doi.org/10.1021/nn503893j
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