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Nanostructured VO2 Photocatalysts for Hydrogen Production
Abstract
Vanadium dioxide (VO(2)) is a well-known semiconductor material with a band gap of 0.7 eV, and is seldom used as a photocatalyst. We report here a new crystal structure for nanostructured VO(2), with body-centered-cubic (bcc) structure and a large optical band gap of approximately 2.7 eV, which surprisingly shows excellent photocatalytic activity in hydrogen production. The bcc VO(2) phase exhibited a high quantum efficiency of approximately 38.7% when synthesized as nanorods. Using films of the aligned VO(2) nanorods, the hydrogen production rate can be tuned by varying the incident angle of UV light on the films and reaches a high rate of 800 mmol/m(2)/h from a mixture of water and ethanol under UV light, at a power density of approximately 27 mW/cm(2), allowing possible commercial application of this material as photoassisted hydrogen generators.
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Cites
A realizable renewable energy future
Turner, J. A. (1999) · Science · doi:10.1126/science.285.5428.687 · Cited by 1,642
Cited by
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
A review of Raman spectroscopy of vanadium oxides
Shvets, P., Dikaya, O., Maksimova, K., & Goikhman, A. (2019) · Journal of Raman Spectroscopy · doi:10.1002/jrs.5616 · Cited by 561
Nanostructured materials for photocatalytic hydrogen production
Zhu, J., & Zäch, M. (2009) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2009.05.003 · Cited by 406
Designer Titania-Supported Au–Pd Nanoparticles for Efficient Photocatalytic Hydrogen Production
Su, R., Tiruvalam, R., Logsdail, A. J., He, Q., Downing, C. A., Jensen, M. T., Dimitratos, N., Kesavan, L., Wells, P. P., Bechstein, R., et al. (2014) · ACS Nano · doi:10.1021/nn500963m · Cited by 306
Metadata
- Authors
- Wang, Y., Zhang, Z., Zhu, Y., Li, Z., Vajtai, R., Ci, L., & Ajayan, P. M.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-07-01
- Volume
- 2
- Issue
- 7
- Pages
- 1492-1496
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2055090375
- Cited by
- 171
- References
- 1
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- closed
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