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One-Pot Synthesis of Fluorescent Carbon Nanoribbons, Nanoparticles, and Graphene by the Exfoliation of Graphite in Ionic Liquids
Abstract
In this work we demonstrate a facile means to generate fluorescent carbon nanoribbons, nanoparticles, and graphene from graphite electrode using ionic liquid-assisted electrochemical exfoliation. A time-dependence study of products exfoliated from the graphite anode allows the reconstruction of the exfoliation mechanism based on the interplay of anodic oxidation and anion intercalation. We have developed strategies to control the distribution of the exfoliated products. In addition, the fluorescence of these carbon nanomaterials can be tuned from the visible to ultraviolet region by controlling the water content in the ionic liquid electrolyte.
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Citations
Cites
One-step synthesis of fluorescent carbon nanoparticles by laser irradiation
Hu, S.-L., Niu, K.-Y., Sun, J., Yang, J., Zhao, N.-Q., & Du, X.-W. (2009) · J. Mater. Chem. · doi:10.1039/b812943f · Cited by 968
Self-citation
Cited by
Luminescent Carbon Nanodots: Emergent Nanolights
Baker, S. N., & Baker, G. A. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200906623 · Cited by 4,921
Zhu, S., Song, Y., Zhao, X., Shao, J., Zhang, J., & Yang, B. (2015) · Nano Research · doi:10.1007/s12274-014-0644-3 · Cited by 2,781
Glowing Graphene Quantum Dots and Carbon Dots: Properties, Syntheses, and Biological Applications
Zheng, X. T., Ananthanarayanan, A., Luo, K. Q., & Chen, P. (2015) · Small · doi:10.1002/smll.201402648 · Cited by 2,190
Georgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Carbon dots—Emerging light emitters for bioimaging, cancer therapy and optoelectronics
Hola, K., Zhang, Y., Wang, Y., Giannelis, E. P., Zboril, R., & Rogach, A. L. (2014) · Nano Today · doi:10.1016/j.nantod.2014.09.004 · Cited by 992
Metadata
- Authors
- Lu, J., Yang, J.-X., Wang, J., Lim, A., Wang, S., & Loh, K. P.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-08-05
- Volume
- 3
- Issue
- 8
- Pages
- 2367-2375
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1986410538
- Cited by
- 1,203
- References
- 1
- FWCI
- 23.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lu, J., Yang, J.-X., Wang, J., Lim, A., Wang, S., & Loh, K. P. (2009). One-Pot Synthesis of Fluorescent Carbon Nanoribbons, Nanoparticles, and Graphene by the Exfoliation of Graphite in Ionic Liquids. ACS Nano. https://doi.org/10.1021/nn900546b
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