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Organic Synthesis in Ionic Liquids: The Stille Coupling
Abstract
[figure: see text] The Stille coupling reaction has been performed in 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM BF4), a room-temperature ionic liquid (RTIL). Use of this solvent system allows for facile recycling of the solvent and catalyst system, which can be used at least five times with little loss in activity. An interesting preference in starting catalyst oxidation state for use with aryl bromides and aryl iodides was observed.
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Citations
Cited by
Pârvulescu, V. I., & Hardacre, C. (2007) · Chemical Reviews · doi:10.1021/cr050948h · Cited by 2,377
Ionic liquids: applications in catalysis
Zhao, D., Wu, M., Kou, Y., & Min, E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00541-7 · Cited by 1,049
Recovery and purification of ionic liquids from solutions: a review
Zhou, J., Sui, H., Jia, Z., Yang, Z., He, L., & Li, X. (2018) · RSC Advances · doi:10.1039/c8ra06384b · Cited by 292
Byrne, N., Wang, L.-M., Belieres, J.-P., & Angell, C. A. (2007) · Chem. Commun. · doi:10.1039/b618943a · Cited by 223
Ionic Liquids as Solvents for Rhodium and Platinum Catalysts Used in Hydrosilylation Reaction
Zielinski, W., Kukawka, R., Maciejewski, H., & Smiglak, M. (2016) · Molecules · doi:10.3390/molecules21091115 · Cited by 30
Metadata
- Authors
- Handy, S. T., & Zhang, X.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-01-01
- Volume
- 3
- Issue
- 2
- Pages
- 233-236
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2041964044
- Cited by
- 168
- References
- 0
- FWCI
- 7.04
- Type
- journal article
- Language
- en
- Open access
- closed
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