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(Salen)chromium(III)/DMAP: An Efficient Catalyst System for the Selective Synthesis of 5-Substituted Oxazolidinones from Carbon Dioxide and Aziridines
Abstract
[reaction: see text] (Salen)chromium(III)/DMAP was found to be an active catalyst system for the coupling of CO(2) and aziridines. The oxazolidinone products were produced in high yield and selectivity from the opening of the aziridine at the most substituted N-C bond. This catalyst system worked well for a wide variety of monosubstituted N-aryl and N-alkyl aziridines as well as a 2,3-disubstituted N-alkyl aziridine.
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Citations
Cited by
Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion
Yang, Z.-Z., He, L.-N., Gao, J., Liu, A.-H., & Yu, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02774g · Cited by 520
Metadata
- Authors
- Miller, A. W., & Nguyen, S. T.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-06-09
- Volume
- 6
- Issue
- 14
- Pages
- 2301-2304
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W1978463739
- Cited by
- 161
- References
- 0
- FWCI
- 4.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: (Salen)chromium(III)/DMAP: An Efficient Catalyst System for the Selective Synthesis of 5-Substituted Oxazolidinones from Carbon Dioxide and Aziridines. https://app.cochat.ai/papers/10.1021/ol049689t
- The paper
- Miller, A. W., & Nguyen, S. T. (2004). (Salen)chromium(III)/DMAP: An Efficient Catalyst System for the Selective Synthesis of 5-Substituted Oxazolidinones from Carbon Dioxide and Aziridines. Organic Letters. https://doi.org/10.1021/ol049689t
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.