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Gold(I)-Catalyzed Formation of 4-Alkylidene-1,3-dioxolan-2-ones from Propargylic tert-Butyl Carbonates
Abstract
[reaction: see text]. A study concerning the gold(I)-catalyzed rearrangement of propargylic tert-butyl carbonates into 4-alkylidene-1,3-dioxolan-2-ones is described. The mild reaction conditions employed allow the efficient synthesis of a variety of cyclic carbonates that would be less conveniently obtained using reported methods. Variability in the structure of the final product has been observed and is significantly dependent on the nature of the substituent attached to the alkyne moiety.
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Citations
Cited by
Hashmi, A. S. K., & Hutchings, G. J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602454 · Cited by 3,423
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Evano, G., Coste, A., & Jouvin, K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905817 · Cited by 812
Zhang, Z., Liu, C., Kinder, R. E., Han, X., Qian, H., & Widenhoefer, R. A. (2006) · Journal of the American Chemical Society · doi:10.1021/ja062045r · Cited by 459
Metadata
- Authors
- Buzas, A., & Gagosz, F.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-01-12
- Volume
- 8
- Issue
- 3
- Pages
- 515-518
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2075855298
- Cited by
- 195
- References
- 0
- FWCI
- 12.56
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Gold(I)-Catalyzed Formation of 4-Alkylidene-1,3-dioxolan-2-ones from Propargylic tert-Butyl Carbonates. https://app.cochat.ai/papers/10.1021/ol053100o
- The paper
- Buzas, A., & Gagosz, F. (2006). Gold(I)-Catalyzed Formation of 4-Alkylidene-1,3-dioxolan-2-ones from Propargylic tert-Butyl Carbonates. Organic Letters. https://doi.org/10.1021/ol053100o
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