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Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes
Open accessAbstract
During continuing studies with a novel oxidative gold oxyarylation reaction, arylsilanes were found to be competent coupling partners, providing further evidence for an intramolecular electrophilic aromatic substitution mechanism. While providing yields complementary to those of the previously described boronic acid methods, the use of trimethylsilanes reduces the observation of homocoupling byproducts and allows for facile intramolecular coupling reactions.
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Cited by
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Shu, X.-Z., Zhang, M., He, Y., Frei, H., & Toste, F. D. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500716j · Cited by 435
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Jachak, G. R., Ramesh, R., Sant, D. G., Jorwekar, S. U., Jadhav, M. R., Tupe, S. G., Deshpande, M. V., & Reddy, D. S. (2015) · ACS Medicinal Chemistry Letters · doi:10.1021/acsmedchemlett.5b00245 · Cited by 52
Metadata
- Authors
- Brenzovich, W. E., Brazeau, J.-F., & Toste, F. D.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-29
- Volume
- 12
- Issue
- 21
- Pages
- 4728-4731
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2045127893
- Cited by
- 168
- References
- 0
- FWCI
- 8.37
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes. https://app.cochat.ai/papers/10.1021/ol102194c
- The paper
- Brenzovich, W. E., Brazeau, J.-F., & Toste, F. D. (2010). Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes. Organic Letters. https://doi.org/10.1021/ol102194c
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
