The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
High-Temperature Organic Reactions at Room Temperature Using Plasmon Excitation: Decomposition of Dicumyl Peroxide
Abstract
Photoexcitation of gold nanoparticles in their plasmon transition around 530 nm provides the means to carry high-energy reactions at room temperature. In the case of dicumyl peroxide (with activation energy of 34.3 kcal/mol) the reaction occurs in less than 1 min under 532 nm laser excitation. The results suggest that the peroxide is exposed to temperatures of ~500 °C for submicrosecond times, and provides a guide as to which type of organic reactions may benefit from plasmon-mediated energy delivery.
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Cites
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Cited by
Heterometallic antenna−reactor complexes for photocatalysis
Swearer, D. F., Zhao, H., Zhou, L., Zhang, C., Robatjazi, H., Martirez, J. M. P., Krauter, C. M., Yazdi, S., McClain, M. J., Ringe, E., et al. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1609769113 · Cited by 528
Applications and challenges of thermoplasmonics
Baffou, G., Cichos, F., & Quidant, R. (2020) · Nature Materials · doi:10.1038/s41563-020-0740-6 · Cited by 470
Gao, M., Connor, P. K. N., & Ho, G. W. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00971a · Cited by 447
Plasmon-enhanced chemical reactions
Xiao, M., Jiang, R., Wang, F., Fang, C., Wang, J., & Yu, J. C. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta01450a · Cited by 287
Ultrafast Thermal Analysis of Surface Functionalized Gold Nanorods in Aqueous Solution
Huang, J., Park, J., Wang, W., Murphy, C. J., & Cahill, D. G. (2013) · ACS Nano · doi:10.1021/nn304738u · Cited by 83
Metadata
- Authors
- Fasciani, C., Alejo, C. J. B., Grenier, M., Netto-Ferreira, J. C., & Scaiano, J. C.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-10
- Volume
- 13
- Issue
- 2
- Pages
- 204-207
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2322630848
- Cited by
- 163
- References
- 1
- FWCI
- 3.98
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
