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Synthesis of Isoindigo-Based Oligothiophenes for Molecular Bulk Heterojunction Solar Cells
Abstract
Isoindigo, as a new electron acceptor unit for organic electronic materials, was integrated into two low-energy gap oligothiophenes. Optical and electrochemical studies of the newly synthesized oligomers demonstrate broad absorption through the visible spectrum, along with appropriate energy levels, as desired for light harvesting donors for organic solar cells when blended with [6,6]-phenyl-C(61)-butyric acid methyl ester (PC(60)BM). Molecular heterojunction solar cells were fabricated using these oligomers and exhibit a power conversion efficiency up to 1.76% with a V(oc) of 0.74 V, I(sc) of 6.3 mA/cm(2) and fill factor of 0.38.
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Citations
Cites
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
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Mishra, A., & Bäuerle, P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201102326 · Cited by 1,816
Small molecule semiconductors for high-efficiency organic photovoltaics
Lin, Y., Li, Y., & Zhan, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15313k · Cited by 1,751
Molecular Materials for Organic Photovoltaics: Small is Beautiful
Roncali, J., Leriche, P., & Blanchard, P. (2014) · Advanced Materials · doi:10.1002/adma.201305999 · Cited by 586
Solvent Additives: Key Morphology‐Directing Agents for Solution‐Processed Organic Solar Cells
McDowell, C., Abdelsamie, M., Toney, M. F., & Bazan, G. C. (2018) · Advanced Materials · doi:10.1002/adma.201707114 · Cited by 513
Lei, T., Cao, Y., Zhou, X., Peng, Y., Bian, J., & Pei, J. (2012) · Chemistry of Materials · doi:10.1021/cm300117x · Cited by 308
Metadata
- Authors
- Mei, J., Graham, K. R., Stalder, R., & Reynolds, J. R.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-25
- Volume
- 12
- Issue
- 4
- Pages
- 660-663
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2025344514
- Cited by
- 457
- References
- 1
- FWCI
- 33.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mei, J., Graham, K. R., Stalder, R., & Reynolds, J. R. (2010). Synthesis of Isoindigo-Based Oligothiophenes for Molecular Bulk Heterojunction Solar Cells. Organic Letters. https://doi.org/10.1021/ol902512x
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