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In Situ Formation of Mixed Phosphine−Imidazolylidene Palladium Complexes in Room-Temperature Ionic Liquids
Abstract
The in situ formation of a mixed phosphine−imidazolylidene palladium complex, 3, in the room-temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF 4 ]) has been observed under conditions employed in many palladium-catalyzed coupling reactions. This paper highlights the noninnocent nature of imidazolium-based ionic liquids and the implications of this for ionic liquid mediated palladium catalysis.
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Citations
Cited by
Phan, N. T. S., Van Der Sluys, M., & Jones, C. W. (2006) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200505473 · Cited by 1,905
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Welton, T. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.04.015 · Cited by 1,609
Self-citationIonic liquids: applications in catalysis
Zhao, D., Wu, M., Kou, Y., & Min, E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00541-7 · Cited by 1,049
Are Ionic Liquids Chemically Stable?
Wang, B., Qin, L., Mu, T., Xue, Z., & Gao, G. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00594 · Cited by 665
Metadata
- Authors
- Mathews, C. J., Smith, P. J., Welton, T., White, A. J. P., & Williams, D. J.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-07-31
- Volume
- 20
- Issue
- 18
- Pages
- 3848-3850
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2073739546
- Cited by
- 185
- References
- 0
- FWCI
- 15.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mathews, C. J., Smith, P. J., Welton, T., White, A. J. P., & Williams, D. J. (2001). In Situ Formation of Mixed Phosphine−Imidazolylidene Palladium Complexes in Room-Temperature Ionic Liquids. Organometallics. https://doi.org/10.1021/om0105223
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