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Lactide Polymerization with Chiral β-Diketiminate Zinc Complexes
Abstract
N, N ′-Di( S -phenylethyl)-2-amino-4-iminopent-2-ene, S,S - nacnac CH(Me)Ph H, 1a, and N, N ′-dibenzyl-2-amino-4-iminopent-2-ene, nacnac Bn H, 1b, react with ZnEt 2 to form the corresponding nacnac ZnEt complexes 2a and 2b . Neither complex is reactive with 2-propanol or methyl lactate to produce the corresponding alkoxide complexes. In reactions with 2b, ligand redistribution occurs and nacnac Bn 2 Zn was obtained. Reaction of 1a and 1b with Zn(N(SiMe 3 ) 2 ) 2 yielded nacnac ZnN(SiMe 3 ) 2, 6a and 6b . From further reactions with 2-propanol nacnac ZnO i Pr, 7a and 7b, were obtained. Both complexes were catalytically active for polymerization of rac -lactide with apparent first-order rate constants of k app = 0.013−0.019 min −1 and 0.019−0.038 min −1 for 7a and 7b, respectively. Obtained polymers were highly heterotactic, with P r = 0.84−0.87 ( 7a ) and 0.65−0.71 ( 7b ). Analysis of remaining monomer after 75% conversion showed negligible ee and indicates that chiral 7a does not show enantioselectivity in rac -lactide polymerization. Complex 7a, but not 7b, catalyzes unselective transesterification of the polymer during and after polymerization. PLA microstructures in polymerizations with 7b were independent of temperature (23 or 0 °C) or monomer/catalyst ratio (100:1 to 400:1). However, slightly higher P r values were obtained in the presence of 10−100 equiv of MeCN or pyridine. Complexes nacnac Bn 2 Zn, 2b, 6b, and 7a were characterized by an X-ray diffraction study.
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Citations
Cites
Controlled Ring-Opening Polymerization of Lactide and Glycolide
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Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
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Biocompatible Initiators for Lactide Polymerization
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Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization
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Tabthong, S., Nanok, T., Sumrit, P., Kongsaeree, P., Prabpai, S., Chuawong, P., & Hormnirun, P. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01381 · Cited by 64
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Lai, F.-J., Chiu, L.-L., Lee, C.-L., Lu, W.-Y., Lai, Y.-C., Ding, S., Chen, H.-Y., & Wu, K.-H. (2019) · Polymer · doi:10.1016/j.polymer.2019.121812 · Cited by 17
Metadata
- Authors
- Drouin, F., Oguadinma, P. O., Whitehorne, T. J. J., Prud’homme, R. E., & Schaper, F.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-04-15
- Volume
- 29
- Issue
- 9
- Pages
- 2139-2147
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2028601002
- Cited by
- 165
- References
- 7
- FWCI
- 7.32
- Type
- journal article
- Language
- en
- Open access
- closed
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