The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Synthesis of Highly Stable 1,3-Diaryl-1 H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium-Catalyzed Olefin Metathesis
Open accessAbstract
The formal cycloaddition between 1,3-diaza-2-azoniaallene salts and alkynes or alkyne equivalents provides an efficient synthesis of 1,3-diaryl-1H-1,2,3-triazolium salts, the direct precursors of 1,2,3-triazol-5-ylidenes. These N,N-diarylated mesoionic carbenes (MICs) exhibit enhanced stability in comparison to their alkylated counterparts. Experimental and computational results confirm that these MICs act as strongly electron-donating ligands. Their increased stability allows for the preparation of ruthenium olefin metathesis catalysts that are efficient in both ring-opening and ring-closing reactions.
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Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe
Schleyer, P. V. R., Maerker, C., Dransfeld, A., Jiao, H., & van Eikema Hommes, N. J. R. (1996) · Journal of the American Chemical Society · doi:10.1021/ja960582d · Cited by 6,210
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A Brief Survey of Our Contribution to Stable Carbene Chemistry
Martin, D., Melaimi, M., Soleilhavoup, M., & Bertrand, G. (2011) · Organometallics · doi:10.1021/om200650x · Cited by 422
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Metadata
- Authors
- Bouffard, J., Keitz, B. K., Tonner, R., Guisado-Barrios, G., Frenking, G., Grubbs, R. H., & Bertrand, G.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-13
- Volume
- 30
- Issue
- 9
- Pages
- 2617-2627
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W1970752875
- Cited by
- 218
- References
- 2
- FWCI
- 10.62
- Type
- journal article
- Language
- en
- Open access
- green
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- Bouffard, J., Keitz, B. K., Tonner, R., Guisado-Barrios, G., Frenking, G., Grubbs, R. H., & Bertrand, G. (2011). Synthesis of Highly Stable 1,3-Diaryl-1 H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. https://doi.org/10.1021/om200272m
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