The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Hydrogen Bonding in Organometallic Crystals. 6. X−H---M Hydrogen Bonds and M---(H−X) Pseudo-Agostic Bonds
Abstract
The intermolecular interactions between X−H groups (X = C, N, and O) and metal atoms in crystalline organometallic complexes have been investigated. Molecular and crystal structures determined by neutron and/or X-ray diffraction data have been retrieved from the Cambridge Structural Database. The comparative analysis of intermolecular H---M and X---M distances as well as that of the X−H---M angles allows a discrimination between the behavior of electrophilic and nucleophilic metal centers. Two novel types of interactions have been characterized: (i) the intermolecular multicenter hetero-acceptor (IMH) hydrogen bond formed when the X−H donor group interacts with M−X‘ n systems where M is an electron-rich metal and X‘ a metal-coordinated electronegative atom (X‘ = S, N, O, Cl); (ii) the intermolecular pseudo-agostic (IPA) interaction in which the X−H bond can donate electron density to electron deficient metal atoms M---(H-X) as observed in intramolecular agostic interactions. Hydrogen bonding to metal centers in neutral complexes (X−H---M) have been compared with charge assisted (X−H + ---M - ) hydrogen bonds involving electron-rich anionic complexes.
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Cites
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Cited by
Applications of the Cambridge Structural Database to molecular inorganic chemistry
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Metadata
- Authors
- Braga, D., Grepioni, F., Tedesco, E., Biradha, K., & Desiraju, G. R.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-04-01
- Volume
- 16
- Issue
- 9
- Pages
- 1846-1856
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2079291093
- Cited by
- 317
- References
- 15
- FWCI
- 8.04
- Type
- journal article
- Language
- en
- Open access
- closed
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