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Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization
Abstract
The α-diimine ligand ArN C(Me)C(Me) NAr (Ar = 2,6-C 6 H 3 - i Pr 2 ) reacts with Pd(OAc) 2 in the presence of HBF 4 ·Et 2 O, or [Pd(MeCN) 4 ](BF 4 ) 2 in the absence of acid, to give ethylene polymerization catalysts. The reactions of a related β-diimine ligand with [Pd(MeCN) 4 ](BF 4 ) 2 and (1,2-dimethoxyethane)NiBr 2, and the polymerization activity of catalysts derived from it, are discussed.
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Citations
Cited by
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207
The Chemistry of β-Diketiminatometal Complexes
Bourget-Merle, L., Lappert, M. F., & Severn, J. R. (2002) · Chemical Reviews · doi:10.1021/cr010424r · Cited by 1,049
Metadata
- Authors
- Feldman, J., McLain, S. J., Parthasarathy, A., Marshall, W. J., Calabrese, J. C., & Arthur, S. D.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-04-01
- Volume
- 16
- Issue
- 8
- Pages
- 1514-1516
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W1978815693
- Cited by
- 346
- References
- 0
- FWCI
- 11.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization. https://app.cochat.ai/papers/10.1021/om960968x
- The paper
- Feldman, J., McLain, S. J., Parthasarathy, A., Marshall, W. J., Calabrese, J. C., & Arthur, S. D. (1997). Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene Polymerization. Organometallics. https://doi.org/10.1021/om960968x
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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