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Fine Chemicals from Lignosulfonates. 1. Synthesis of Vanillin by Oxidation of Lignosulfonates
Abstract
The oxidation of lignosulfonates (LS) to vanillin by persulphate, oxygen, and a variety of catalytic systems has been investigated. Cobalt and copper catalysts appeared to be the most effective in the oxidation by oxygen. An investigation where multivariate mathematical and statistical design and modelling have been used for the process optimisation has led to the development of a multivariate mathematical model which describes the oxidation process with high predictive capacity. By using this model, an increase of the vanillin yield from 4.1% of the current procedure to 7.2% is obtained, this corresponding to 75% relative improvement of the yield.
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Citations
Cites
Use of Half-Normal Plots in Interpreting Factorial Two-Level Experiments
Daniel, C. (1959) · Technometrics · doi:10.1080/00401706.1959.10489866 · Cited by 798
Cited by
Vanillin production from lignin and its use as a renewable chemical
Fache, M., Boutevin, B., & Caillol, S. (2016) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.5b01344 · Cited by 902
Current challenges in commercially producing biofuels from lignocellulosic biomass
Balan, V. (2014) · ISRN Biotechnology · doi:10.1155/2014/463074 · Cited by 551
Vanillin, a promising biobased building-block for monomer synthesis
Fache, M., Darroman, E., Besse, V., Auvergne, R., Caillol, S., & Boutevin, B. (2014) · Green Chem. · doi:10.1039/c3gc42613k · Cited by 499
Degradation of vanillin during lignin valorization under alkaline oxidation
Zhu, Y., Liu, J., Liao, Y., Lv, W., Ma, L., & Wang, C. (2018) · Topics in Current Chemistry · doi:10.1007/s41061-018-0208-1 · Cited by 46
Metadata
- Authors
- Bjørsvik, H.-R., & Minisci, F.
- Venue
- Organic Process Research & Development
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-08-04
- Volume
- 3
- Issue
- 5
- Pages
- 330-340
- ISSN
- 1083-6160 (ISSN-L)
- 1520-586X
- OpenAlex
- W2062306736
- Cited by
- 189
- References
- 1
- FWCI
- 2.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bjørsvik, H.-R., & Minisci, F. (1999). Fine Chemicals from Lignosulfonates. 1. Synthesis of Vanillin by Oxidation of Lignosulfonates. Organic Process Research & Development. https://doi.org/10.1021/op9900028
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.