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Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Alkane Fuels over Bifunctional Zeolite-Supported Metal Catalysts
Abstract
A bifunctional catalyst of Ru supported in zeolite HZSM-5, Ru/HZSM-5 (Si/Al = 25), exhibited excellent hydrodeoxygenation activity toward the conversion of lignin-derived phenolic monomers and dimers to cycloalkanes in aqueous solution. The oxygen-containing groups in mono- and binuclear phenols were removed through a cleavage of C–O bonds in phenolics followed by an integrated metal- and acid-catalyzed hydrogenation and dehydration. As a bifunctional catalyst Ru/HZSM-5, the presence of both the Brønsted acid site in the pores of HZSM-5 for dehydration and a metallic function of Ru for hydrogenation was indispensible for the formation of alkanes from lignin-derived phenolics. Our findings also reveal that the Ru/HZSM-5 with the lowest Si/Al ratio of HZSM-5 proved to be most selective to cycloalkanes, indicating that more acid sites over zeolite are favorable for the dehydration of cyclohexanol during hydrodeoxygenation process, which leads higher selectivity to hydrocarbons. This approach for the construction of bifunctional catalyst highlights an efficient route for hydrodeoxygenation of lignin-derived phenolic oil to transportation biofuels.
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Cites
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
Mohan, D., Pittman, C. U., & Steele, P. H. (2006) · Energy & Fuels · doi:10.1021/ef0502397 · Cited by 5,663
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Catalytic conversion of biomass to monofunctional hydrocarbons and targeted liquid-fuel classes
Kunkes, E. L., Simonetti, D. A., West, R. M., Serrano-Ruiz, J. C., Gärtner, C. A., & Dumesic, J. A. (2008) · Science · doi:10.1126/science.1159210 · Cited by 895
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Downstream processing of lignin derived feedstock into end products
Wong, S. S., Shu, R., Zhang, J., Liu, H., & Yan, N. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00134a · Cited by 528
De, S., Saha, B., & Luque, R. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2014.09.065 · Cited by 359
Bio-oil from fast pyrolysis of lignin: Effects of process and upgrading parameters
Fan, L., Zhang, Y., Liu, S., Zhou, N., Chen, P., Cheng, Y., Addy, M., Lu, Q., Omar, M. M., Liu, Y., et al. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.05.129 · Cited by 265
Highly Stable Nb2O5–Al2O3 Composites Supported Pt Catalysts for Hydrodeoxygenation of Diphenyl Ether
Guan, W., Chen, X., Jin, S., Li, C., Tsang, C.-W., & Liang, C. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03736 · Cited by 67
Metadata
- Authors
- Zhang, W., Chen, J., Liu, R., Wang, S., Chen, L., & Li, K.
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-07
- Volume
- 2
- Issue
- 4
- Pages
- 683-691
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2320346315
- Cited by
- 254
- References
- 3
- FWCI
- 9.03
- Type
- journal article
- Language
- en
- Open access
- closed
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