Application of Gibbs Energy Minimization to ModelEarly-Diagenetic Solid-Solution Aqueous-Solution EquilibriaInvolving Authigenic Rhodochrosites in Anoxic BalticSea Sediments
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The stoichiometric solubility product for (Mn,Ca)CO3 solid solutions in Baltic Sea sediments was calculated using a common ratio of Mn0.74Ca0.26CO3.
“The stoichiometric solubility product ( K st) was calculated using Mn0 : 74Ca0 : 26CO3 (Kulik et al., 2000) as a common ratio measured for (Mn, Ca) CO3 solid solutions in Baltic Sea sediments.”
From Are recent changes in sediment manganese sequestration in the euxinic basins of the Baltic Sea linked to the expansion of hypoxia? (2015) · cites this paper as Kulik et al., 2000
Natural calcian rhodochrosite and manganoan calcite have a complete component range between calcite and rhodochrosite.
“Conversely, natural calcian rhodochrosite and manganoan calcite have been reported to have a complete component range between calcite and rhodochrosite [4, 12]”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [12]
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References 70 · Cited by 42
- Authors
- Kulik, D. A., Kersten, M., Heiser, U., & Neumann, T.
- Affiliations
- Leibniz Institute for Baltic Sea Research Warnemünde (DE)
- Johannes Gutenberg University Mainz (DE)
- Karlsruhe Institute of Technology (DE)
- Venue
- Aquatic Geochemistry
- Published
- 2000-06
- Volume
- 6
- Issue
- 2
- Pages
- 147-199
- ISSN
- 1380-6165 (ISSN-L)
- 1573-1421
- OpenAlex
- W332822904
- Cited by
- 42
- References
- 70
- Citations by year
- 2023: 2 · 2021: 3 · 2020: 1 · 2019: 1 · 2018: 1 · 2016: 1 · 2015: 2 · 2014: 1 · 2013: 2 · 2012: 3
- FWCI
- 5.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Aquatic Geochemistry (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Environmental Science › Environmental Chemistry › Methane Hydrates and Related Phenomena
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- early diagenesis, Gibbs free energy minimization, porewater geochemistry, anoxic marine sediments, Gotland Deep, Baltic Sea sediments, mackinawite, greigite, authigenic carbonates, dissolved manganese, redox buffering, distribution coefficient, thermodynamic modeling
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