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Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum
Open accessAbstract
Olivine is an important host of hydrogen in the Earth's upper mantle, and the OH abundance in this mineral determines many important physical properties of the planet's interior. To date, natural and experimentally hydrated olivines have been analyzed by uncalibrated spectroscopic methods with large (±100%) uncertainties in accuracy. We determined the hydrogen contents of three natural olivines by 15 N nuclear reaction analysis and used the results to calibrate the common infrared (IR) spectroscopic method for quantitative hydrogen analysis of olivine. OH content (expressed as parts per million H 2 O by weight) is 0.188 times the total integrated absorbance of the fundamental OH stretching bands in the 3750–3100 cm−1 region. The results indicate that an upward revision of some previous determinations by factors of between 2 and 4 is necessary. The most hydrous naturally occurring mantle‐derived olivine analyzed to date contains 240 ppm wt. H 2 O. Retrospective application of this calibration to experimentally hydrated olivines may be limited by spectral differences in some cases and by the previous use of nonpolarized IR spectra.
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Cited by
WATER, MELTING, AND THE DEEP EARTH H2O CYCLE
Hirschmann, M. M. (2006) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev.earth.34.031405.125211 · Cited by 631
Effect of water and stress on the lattice-preferred orientation of olivine
Jung, H., Katayama, I., Jiang, Z., Hiraga, T., & Karato, S. (2006) · Tectonophysics · doi:10.1016/j.tecto.2006.02.011 · Cited by 400
Water and its influence on the lithosphere–asthenosphere boundary
Green, D. H., Hibberson, W. O., Kovács, I., & Rosenthal, A. (2010) · Nature · doi:10.1038/nature09369 · Cited by 366
Hydrogen partition coefficients between nominally anhydrous minerals and basaltic melts
Aubaud, C., Hauri, E. H., & Hirschmann, M. M. (2004) · Geophysical Research Letters · doi:10.1029/2004gl021341 · Cited by 351
Dehydration melting of nominally anhydrous mantle: The primacy of partitioning
Hirschmann, M. M., Tenner, T., Aubaud, C., & Withers, A. C. (2009) · Physics of the Earth and Planetary Interiors · doi:10.1016/j.pepi.2009.04.001 · Cited by 314
Metadata
- Authors
- Bell, D. R., Rossman, G. R., Maldener, J., Endisch, D., & Rauch, F.
- Venue
- Journal of Geophysical Research: Solid Earth
- Publisher
- American Geophysical Union (AGU)
- Published
- 2003-02
- Volume
- 108
- Issue
- B2
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2025516624
- Cited by
- 474
- References
- 0
- FWCI
- 16.10
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Bell, D. R., Rossman, G. R., Maldener, J., Endisch, D., & Rauch, F. (2003). Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysical Research: Solid Earth. https://doi.org/10.1029/2001jb000679
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