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Atmospheric chemistry of a 33–34 hour old volcanic cloud from Hekla Volcano (Iceland): Insights from direct sampling and the application of chemical box modeling
Abstract
On 28 February 2000, a volcanic cloud from Hekla volcano, Iceland, was serendipitously sampled by a DC‐8 research aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE I). It was encountered at night at 10.4 km above sea level (in the lower stratosphere) and 33–34 hours after emission. The cloud is readily identified by abundant SO2 (≤1 ppmv), HCl (≤70 ppbv), HF (≤60 ppbv), and particles (which may have included fine silicate ash). We compare observed and modeled cloud compositions to understand its chemical evolution. Abundances of sulfur and halogen species indicate some oxidation of sulfur gases but limited scavenging and removal of halides. Chemical modeling suggests that cloud concentrations of water vapor and nitric acid promoted polar stratospheric cloud (PSC) formation at 201–203 K, yielding ice, nitric acid trihydrate (NAT), sulfuric acid tetrahydrate (SAT), and liquid ternary solution H2SO4/H2O/HNO3 (STS) particles. We show that these volcanically induced PSCs, especially the ice and NAT particles, activated volcanogenic halogens in the cloud producing >2 ppbv ClOx. This would have destroyed ozone during an earlier period of daylight, consistent with the very low levels of ozone observed. This combination of volcanogenic PSCs and chlorine destroyed ozone at much faster rates than other PSCs that Arctic winter. Elevated levels of HNO3 and NOy in the cloud can be explained by atmospheric nitrogen fixation in the eruption column due to high temperatures and/or volcanic lightning. However, observed elevated levels of HOx remain unexplained given that the cloud was sampled at night.
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From Serpentinization as the source of energy, electrons, organics, catalysts, nutrients and pH gradients for the origin of LUCA and life (2023) · cites this paper as Rose et al., 2006
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Cites
Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 18
Burkholder, J. B., Sander, S. P., Abbatt, J. P. D., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H. (2015) · doi:10.13140/rg.2.1.2504.2806 · Cited by 1,928
Nitrogen oxides in the troposphere: Global and regional budgets
Logan, J. A. (1983) · Journal of Geophysical Research Atmospheres · doi:10.1029/jc088ic15p10785 · Cited by 868
Laboratory studies of the nitric acid trihydrate: Implications for the south polar stratosphere
Hanson, D. R., & Mauersberger, K. (1988) · Geophysical Research Letters · doi:10.1029/gl015i008p00855 · Cited by 759
Volcanic-gas studies: Methods, results, and applications
Symonds, R. B., Rose, W. I., Bluth, G. J., & Gerlach, T. M. (1994) · Digital Commons - Michigan Tech (Michigan Technological University) · Cited by 504
Self-citationMultiannual simulations with a three‐dimensional chemical transport model
Chipperfield, M. P. (1999) · Journal of Geophysical Research Atmospheres · doi:10.1029/98jd02597 · Cited by 490
Detection of bromine monoxide in a volcanic plume
Bobrowski, N., Hönninger, G., Galle, B., & Platt, U. (2003) · Nature · doi:10.1038/nature01625 · Cited by 358
Stratospheric aerosols: Observation and theory
TURCO, R. P., Whitten, R. C., & Toon, O. B. (1982) · Reviews of Geophysics · doi:10.1029/rg020i002p00233 · Cited by 338
Estimations of global no, emissions and their uncertainties
Lee, D. S., Köhler, I., Grobler, E. S., Röhrer, F., SAUSEN, R., Gallardo, L., Olivier, J. G. J., Dentener, F. J., & Bouwman, L. (1997) · Atmospheric Environment · doi:10.1016/s1352-2310(96)00327-5 · Cited by 306
Carslaw, K. S., Luo, B., & Peter, T. (1995) · Geophysical Research Letters · doi:10.1029/95gl01668 · Cited by 292
Sander, S. P., Finlayson‐Pitts, B. J., Friedl, R. R., Golden, D. M., Huie, R. E., Keller-Rudek, H., Kolb, C. E., Kurylo, M. J., Molina, M. J., Moortgat, G. K., et al. (2003) · Max Planck Institute for Plasma Physics · Cited by 287
Oskarsson, N. (1980) · Journal of Volcanology and Geothermal Research · doi:10.1016/0377-0273(80)90107-9 · Cited by 252
Contribution of C1- and F-bearing gases to the atmosphere by volcanoes
Symonds, R. B., Rose, W. I., & Reed, M. H. (1988) · Nature · doi:10.1038/334415a0 · Cited by 224
Self-citationStratospheric Chlorine Injection by Volcanic Eruptions: HCl Scavenging and Implications for Ozone
Tabazadeh, A., & TURCO, R. P. (1993) · Science · doi:10.1126/science.260.5111.1082 · Cited by 205
Volcanic sources of tropospheric ozone‐depleting trace gases
Gerlach, T. M. (2004) · Geochemistry Geophysics Geosystems · doi:10.1029/2004gc000747 · Cited by 190
Self-citationModeling the composition of liquid stratospheric aerosols
Carslaw, K. S., Peter, T., & Clegg, S. L. (1997) · Reviews of Geophysics · doi:10.1029/97rg00078 · Cited by 187
Bureau, H., Keppler, H., & Métrich, N. (2000) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(00)00258-2 · Cited by 183
Hobbs, P. V., Radke, L. F., Lyons, J. H., Ferek, R. J., Coffman, D. J., & Casadevall, T. J. (1991) · Journal of Geophysical Research Atmospheres · doi:10.1029/91jd01635 · Cited by 180
Injection of gases into the stratosphere by explosive volcanic eruptions
Textor, C., Graf, H., Herzog, M., & Oberhuber, J. M. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd002987 · Cited by 177
Emission of bromine and iodine from Mount Etna volcano
Aiuppa, A., Federico, C., Franco, A., Giudice, G., Gurrieri, S., Inguaggiato, S., Liuzzo, M., McGonigle, A. J. S., & Valenza, M. (2005) · Geochemistry Geophysics Geosystems · doi:10.1029/2005gc000965 · Cited by 154
Aiuppa, A., Inguaggiato, S., McGonigle, A. J. S., O'Dwyer, M. J., Oppenheimer, C., Padgett, M. J., Rouwet, D., & Valenza, M. (2005) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.09.018 · Cited by 146
Self-citationOxidation of volcanic SO2: A sink for stratospheric OH and H2O
Bekki, S. (1995) · Geophysical Research Letters · doi:10.1029/95gl00534 · Cited by 145
Open‐path, near‐infrared tunable diode laser spectrometer for atmospheric measurements of H2O
May, R. D. (1998) · Journal of Geophysical Research Atmospheres · doi:10.1029/98jd01678 · Cited by 145
The use of trajectory cluster analysis to interpret trace gas measurements at Mace Head, Ireland
Cape, J. N., Methven, J. A., & Hudson, L. E. (2000) · Atmospheric Environment · doi:10.1016/s1352-2310(00)00098-4 · Cited by 141
Nitrogen fixation by volcanic lightning in the early Earth
Navarro-González, R., Molina, M. J., & Molina, L. T. (1998) · Geophysical Research Letters · doi:10.1029/98gl02423 · Cited by 119
An overview of the SOLVE/THESEO 2000 campaign
Newman, P. A., Harris, N., Adriani, A., Amanatidis, G. T., Anderson, J. G., Braathen, G. O., Brune, W. H., Carslaw, K. S., Craig, M. S., DeCola, P. L., et al. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd001303 · Cited by 117
Volcanic gas emissions from Mount Erebus and their impact on the Antarctic environment
Zreda‐Gostynska, G., Kyle, P. R., Finnegan, D. L., & Meeker, K. (1997) · Journal of Geophysical Research Atmospheres · doi:10.1029/97jb00155 · Cited by 114
Weather radar observations of the Hekla 2000 eruption cloud, Iceland
Lacasse, C. M., Karlsdóttir, S., Larsen, G., Soosalu, H., Rose, W. I., & Ernst, G. G. J. (2003) · Bulletin of Volcanology · doi:10.1007/s00445-003-0329-3 · Cited by 114
Self-citationTextor, C., Graf, H., Timmreck, C., & Robock, A. D. (2004) · Advances in global change research · doi:10.1007/978-1-4020-2167-1_7 · Cited by 112
Environmental impacts of tropospheric volcanic gas plumes
Delmelle, P. (2003) · Geological Society London Special Publications · doi:10.1144/gsl.sp.2003.213.01.23 · Cited by 112
The homogeneous chemistry of atmospheric sulfur
Graedel, T. E. (1977) · Reviews of Geophysics · doi:10.1029/rg015i004p00421 · Cited by 103
Volcanic source for fixed nitrogen in the early Earth's atmosphere
Mather, T. A., Pyle, D. M., & Allen, A. G. (2004) · Geology · doi:10.1130/g20679.1 · Cited by 99
Self-citationMather, T. A., Allen, A. G., Davison, B. M., Pyle, D. M., Oppenheimer, C., & McGonigle, A. J. S. (2004) · Earth and Planetary Science Letters · doi:10.1016/s0012-821x(03)00640-x · Cited by 98
Self-citationMoune, S., Gauthier, P., Gislason, S. R., & Sigmarsson, O. (2005) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.09.011 · Cited by 96
Particles and gases in the emissions from the 1980–1981 volcanic eruptions of Mt. St. Helens
Hobbs, P. V., Tuell, J. P., Hegg, D. A., Radke, L. F., & Eltgroth, M. W. (1982) · Journal of Geophysical Research Atmospheres · doi:10.1029/jc087ic13p11062 · Cited by 96
Bekki, S., Pyle, J. A., Zhong, W., Toumi, R., Haigh, J. D., & Pyle, D. M. (1996) · Geophysical Research Letters · doi:10.1029/96gl02088 · Cited by 95
A two‐dimensional modeling study of the volcanic eruption of Mount Pinatubo
Bekki, S., & Pyle, J. A. (1994) · Journal of Geophysical Research Atmospheres · doi:10.1029/94jd00667 · Cited by 94
Horwell, C. J., Sparks, R. S. J., Brewer, T. S., Llewellin, E. W., & Williamson, B. J. (2003) · Bulletin of Volcanology · doi:10.1007/s00445-002-0266-6 · Cited by 91
Volcano fixes nitrogen into plant-available forms
Huebert, B. J., Vitousek, P. M., Sutton, J., Elias, T., Heath, J. A., Coeppicus, S., Howell, S. G., & Blomquist, B. W. (1999) · Biogeochemistry · doi:10.1007/bf00993099 · Cited by 87
A vortex‐scale simulation of the growth and sedimentation of large nitric acid hydrate particles
Carslaw, K. S., Kettleborough, J. A., Northway, M. J., Davies, S., Gao, R. S., Fahey, D. W., Baumgardner, D. G., Chipperfield, M. P., & Kleinböhl, A. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd000467 · Cited by 87
The chemistry of icelandic lava incrustations and the latest stages of degassing
Oskarsson, N. (1981) · Journal of Volcanology and Geothermal Research · doi:10.1016/0377-0273(81)90057-3 · Cited by 87
Thermodynamic stability and phase transitions of PSC particles
Koop, T., Carslaw, K. S., & Peter, T. (1997) · Geophysical Research Letters · doi:10.1029/97gl02148 · Cited by 83
Large loss of total ozone during the Arctic winter of 1999/2000
Sinnhuber, B., Chipperfield, M. P., Davies, S., Burrows, J. P., Eichmann, K. ., Weber, M. C., von der Gathen, P., Guirlet, M., Cahill, G. A., Lee, A. M., et al. (2000) · Geophysical Research Letters · doi:10.1029/2000gl011772 · Cited by 79
Tie, X., Emmons, L. K., Horowitz, L. W., Brasseur, G. P., Ridley, B. A., Atlas, E., Stround, C., Hess, P., Klonecki, A., Madronich, S., et al. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd001508 · Cited by 78
SO2 emissions from basaltic eruptions, and the excess sulfur issue
Sharma, K., Blake, S., Self, S., & Krueger, A. J. (2004) · Geophysical Research Letters · doi:10.1029/2004gl019688 · Cited by 71
The February–March 2000 eruption of Hekla, Iceland from a satellite perspective
Rose, W. I., Gu, Y., Watson, I. M., Yu, T., Blut, G. J. S., Prata, F. J., Krueger, A. J., Krotkov, N. A., Carn, S., Fromm, M. D., et al. (2003) · Geophysical monograph · doi:10.1029/139gm07 · Cited by 70
Self-citationRozanov, E., Schlesinger, M. E., Andronova, N. G., Yang, F., Malyshev, S. L., Zubov, V. A., Egorova, T. A., & Li, B. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd000974 · Cited by 52
Rogers, D. P., Johnson, D. W., & Friehe, C. A. (1995) · Journal of the Atmospheric Sciences · doi:10.1175/1520-0469(1995)052 · Cited by 46
Hunton, D. E., Viggiano, A. A., Miller, T. M., Ballenthin, J. O., Reeves, J. M., Wilson, J. C., Lee, S., Anderson, B. E., Brune, W. H., Harder, H., et al. (2005) · Journal of Volcanology and Geothermal Research · doi:10.1016/j.jvolgeores.2005.01.005 · Cited by 45
Self-citationThe February-March 2000 eruption of Hekla, Iceland from a satellite perspective
Rose, W. C., Gu, Y., Watson, I. M., Yu, T., Bluth, G. J., Prata, F. J., Krueger, A., Krotkov, N. A., Carn, S., Fromm, M. D., et al. (2004) · Ghent University Academic Bibliography (Ghent University) · Cited by 43
Self-citationObservation of stratospheric ozone depletion associated with Delta II rocket emissions
Ross, M. N., Toohey, D. W., Rawlins, W. T., Richard, E. C., Kelly, K. K., Tuck, A. F., Proffitt, M. H., Hagen, D. E., Hopkins, A., Whitefield, P. D., et al. (2000) · Geophysical Research Letters · doi:10.1029/1999gl011159 · Cited by 39
Horrocks, L. A., Oppenheimer, C., Burton, M. R., & Duffell, H. J. (2003) · Geological Society London Special Publications · doi:10.1144/gsl.sp.2003.213.01.21 · Cited by 36
Self-citationModel studies of chlorine deactivation and formation of ClONO2 collar in the Arctic polar vortex
Chipperfield, M. P., Lutman, E. R., Kettleborough, J. A., Pyle, J. A., & Roche, A. E. (1997) · Journal of Geophysical Research Atmospheres · doi:10.1029/96jd00442 · Cited by 35
Modeled Arctic ozone depletion in winter 1997/1998 and comparison with previous winters
Guirlet, M., Chipperfield, M. P., Pyle, J. A., Goutail, F., Pommereau, J., & Kyrö, E. (2000) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd900121 · Cited by 34
Bandy, A. R., Maroulis, P. J., Wilner, L. A., & Torres, A. L. (1982) · Geophysical Research Letters · doi:10.1029/gl009i009p01097 · Cited by 33
Hallar, A. G., Avallone, L. M., Herman, R. L., Anderson, B. E., & Heymsfield, A. J. (2004) · Journal of Geophysical Research Atmospheres · doi:10.1029/2003jd004348 · Cited by 32
Self-citationAl-Saadi, J. A., Pierce, R. B., Fairlie, T. D., Kleb, M. M., Eckman, R. S., GROSE, W. L., Natarajan, M., & Olson, J. R. (2001) · Journal of Geophysical Research Atmospheres · doi:10.1029/2000jd000185 · Cited by 23
In situ observations of ClO near the winter polar tropopause
Thornton, B. F., Toohey, D. W., Avallone, L. M., Harder, H., Martínez, M., Simpas, J. B., Brune, W. H., & Avery, M. A. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd002839 · Cited by 22
Self-citationIn situ HNO3 to NOy instrument comparison during SOLVE
Ballenthin, J. O., Thorn, W. F., Miller, T. M., Viggiano, A. A., Hunton, D. E., Koike, M., Kondo, Y., Takegawa, N., Irie, H., & Ikeda, H. (2003) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd002136 · Cited by 21
Self-citationIntegrating petrologic and remote sensing perspectives on magmatic volatiles and volcanic degassing
Wallace, P., Cam, S. A., Rose, W. I., Bluth, G. J., & Gerlach, T. M. (2003) · Eos · doi:10.1029/2003eo420001 · Cited by 20
Self-citationRedistribution of reactive nitrogen in the Arctic lower stratosphere in the 1999/2000 winter
Koike, M., Kondo, Y., Takegawa, N., Lefèvre, F., Ikeda, H., Irie, H., Hunton, H. D. E., Viggiano, A. A., Miller, T. M., Ballenthin, J. O., et al. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2001jd001089 · Cited by 20
Self-citationOzone depletion potential of CH3Br
Ko, M. K. W., Sze, N. D., Scott, C. J., Rodríguez, J. M., Weisenstein, D. K., & Sander, S. P. (1998) · Journal of Geophysical Research Atmospheres · doi:10.1029/98jd02537 · Cited by 16
Variability of active chlorine in the lowermost Arctic stratosphere
Thornton, B. F., Toohey, D. W., Avallone, L. M., Hallar, A. G., Harder, H., Martínez, M., Simpas, J. B., Brune, W. H., Koike, M., Kondo, Y., et al. (2005) · Journal of Geophysical Research Atmospheres · doi:10.1029/2004jd005580 · Cited by 12
Self-citationOzone loss derived from balloon-borne tracer measurements in the 1999/2000 Arctic winter
Robinson, A. D., Millard, G. A., Danis, F., Guirlet, M., Harris, N., Lee, A. M., McIntyre, J. D., Pyle, J. A., Arvelius, J., Dagnesjo, S., et al. (2005) · Atmospheric chemistry and physics · doi:10.5194/acp-5-1423-2005 · Cited by 9
Self-citationRoss, D. E. M., Pyle, J. A., Harris, N., McIntyre, J. D., Millard, G. A., Robinson, A. D. T., & Busen, R. (2004) · Atmospheric chemistry and physics · doi:10.5194/acp-4-1407-2004 · Cited by 9
Self-citation
Research works printed but not linked: 6
- Arason P., 2005, Lightning during volcanic eruptions in Iceland, Geophys. Res. Abstr., 7
- Delmelle P., 2003, Volcanic Degassing, 381
- Horrocks L. A., 2003, Volcanic Degassing, 349
- Sander S. P., 2003, Evaluation Number 14
- Sparks R. S. J., 1997, Volcanic Plumes
- Symonds R. B., 1994, Volatiles in Magmas, 1
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Metadata
- Authors
- Rose, W. I., Millard, G. A., Mather, T. A., Hunton, D. E., Anderson, B., Oppenheimer, C., Thornton, B. F., Gerlach, T. M., Viggiano, A. A., Kondo, Y., Miller, T. M., & Ballenthin, J. O.
- Affiliations
- Michigan Technological University (US)
- University of Cambridge (GB)
- United States Air Force Research Laboratory (US)
- Langley Research Center (US)
- University of Colorado Boulder (US)
- United States Geological Survey (US)
- Research Center for Advanced Science and Technology, The University of Tokyo (JP)
- ORCID
- Venue
- Journal of Geophysical Research: Atmospheres
- Publisher
- American Geophysical Union (AGU)
- Published
- 2006-10-24
- Volume
- 111
- Issue
- D20
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2160977519
- Cited by
- 116
- References
- 64
- Citations by year
- 2024: 4 · 2023: 11 · 2022: 5 · 2021: 8 · 2020: 3 · 2019: 4 · 2018: 6 · 2017: 7 · 2016: 9 · 2015: 4 · 2014: 9 · 2013: 6 · 2012: 8
- FWCI
- 3.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Digital Commons - Michigan Tech (Michigan Technological University) (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
- Keywords
- volcanic plumes, Hekla volcano, polar stratospheric clouds, stratospheric ozone depletion, chlorine activation, nitric acid trihydrate, sulfur dioxide, hydrogen chloride, hydrogen fluoride, nitric acid, atmospheric nitrogen fixation, volcanic lightning
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