The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Spectral reflectance of carbonate minerals in the visible and near infrared (0.35–2.55 um): Anhydrous carbonate minerals
Abstract
Reflectance spectroscopy in the visible and near infrared (0.35–2.55 um) offers a rapid, inexpensive, nondestructive technique for determining the mineralogy and gaining information on the minor element chemistry of carbonate minerals and rocks. Spectra of all commonly occurring anhydrous end‐member carbonate minerals contain seven strong absorption bands at wavelengths >1.6 um due to vibrations of the carbonate radical. Positions, widths, and spacing between carbonate bands are diagnostic of mineralogy. Differences in positions of carbonate bands between spectra of different minerals are primarily due to differences in mass of the major cation, with cation electronegativity playing a secondary role. Spectra of calcite group minerals may contain absorption features due to transition metal cations such as Fe and Mn, which can also aid in mineral identification. Spectra confirm the occurrence of both cations in the divalent state. Fe 2+ produces a broad feature near 1.1 um whose position and degree of doubling are related to the size and degree of distortion of the octahedral site, as predicted by crystal field theory. Mn 2+ and Fe 2+ produce very strong absorption bands in the minerals for which they are the major cation (rhodochrosite and siderite, respectively), making it easy to distinguish these from other carbonate minerals, even when presence of water bands may make it difficult to determine accurately carbonate band positions.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“By contrast, in Mg-rich carbonates (magnesite or even dolomite) all these spectral features occur at distinctly shorter wavelengths.”
From Orbital evidence for more widespread carbonate-bearing rocks on Mars (2016) · cites this paper as Gaffey, 1987
Citations
Cites
The nature of the chemical bond—1992
Pauling, L. C. (1992) · Journal of Chemical Education · doi:10.1021/ed069p519 · Cited by 13,235
Introduction to Ligand Field Theory
Ballhausen, C. J., & Weiner, M. A. (1963) · Journal of The Electrochemical Society · doi:10.1149/1.2425758 · Cited by 2,600
An accurate X-ray spectrographic method for the analysis of a wide range of geological samples
Norrish, K., & Hutton, J. T. (1969) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(69)90126-4 · Cited by 1,747
Mineralogical Applications of Crystal Field Theory
Burns, R. G. (1993) · Cambridge University Press eBooks · doi:10.1017/cbo9780511524899 · Cited by 1,659
Visible and near-infrared spectra of minerals and rocks: III. Oxides and hydro-oxides
Hunt, G. R. (1971) · Cited by 624
Sedimentary carbonate minerals
(1973) · Earth-Science Reviews · doi:10.1016/0012-8252(73)90031-7 · Cited by 563
Sedimentary Carbonate Minerals
Lippmann, F. (1973) · doi:10.1007/978-3-642-65474-9 · Cited by 545
Inorganic infrared and raman spectra
S, S. (1973) · Journal of Molecular Structure · doi:10.1016/0022-2860(73)80024-9 · Cited by 479
Morris, R. V., Lauer, H. V., Lawson, C. A., Gibson, E. K., Nace, G., & Stewart, C. (1985) · Journal of Geophysical Research Atmospheres · doi:10.1029/jb090ib04p03126 · Cited by 451
White, W. B. (2015) · Mineralogical Society of Great Britain and Ireland eBooks · doi:10.1180/mono-4.12 · Cited by 384
Research works printed but not linked: 3
- Berry S. R., 1980, Physical Chemistry
- Hunt G. R., 1976, Visible and near‐infrared spectra of minerals and rocks, XI, Sedimentary rocks, Mod. Geol., 5, 211
- Pauling L., 1970, General Chemistry
Cited by
Sorted by citations
Orbital Identification of Carbonate-Bearing Rocks on Mars
Ehlmann, B. L., Mustard, J. F., Murchie, S. L., Poulet, F., Bishop, J. L., Brown, A. J., Calvin, W. M., Clark, R. N., Marais, D. J. D., Milliken, R. E., et al. (2008) · Science · doi:10.1126/science.1164759 · Cited by 713
Ehlmann, B. L., Mustard, J. F., Swayze, G. A., Clark, R. N., Bishop, J. L., Poulet, F., Des Marais, D. J., Roach, L. H., Milliken, R. E., Wray, J. J., et al. (2009) · Journal of Geophysical Research: Planets · doi:10.1029/2009je003339 · Cited by 705
Viviano, C. E., Seelos, F. P., Murchie, S. L., Kahn, E. G., Seelos, K. D., Taylor, H. W., Taylor, K., Ehlmann, B. L., Wiseman, S. M., Mustard, J. F., et al. (2014) · Journal of Geophysical Research Planets · doi:10.1002/2014je004627 · Cited by 486
Identification of Carbonate-Rich Outcrops on Mars by the Spirit Rover
Morris, R. V., Ruff, S. W., Gellert, R., Ming, D. W., Arvidson, R. E., Clark, B. C., Golden, D. C., Siebach, K., Klingelhöfer, G., Schröder, C., et al. (2010) · Science · doi:10.1126/science.1189667 · Cited by 447
Quantitative remote sensing of soil properties
Ben‐Dor, E. (2002) · Advances in agronomy · doi:10.1016/s0065-2113(02)75005-0 · Cited by 444
Metadata
- Authors
- Gaffey, S. J.
- Corresponding author
- Gaffey, Susan J.
- Venue
- Journal of Geophysical Research: Solid Earth
- Publisher
- American Geophysical Union (AGU)
- Published
- 1987-02-10
- Volume
- 92
- Issue
- B2
- Pages
- 1429-1440
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2016376046
- Cited by
- 323
- References
- 38
- Citations by year
- 2026: 24 · 2025: 14 · 2024: 10 · 2023: 15 · 2022: 18 · 2021: 20 · 2020: 22 · 2019: 17 · 2018: 12 · 2017: 17 · 2016: 15 · 2015: 16 · 2014: 11 · 2013: 9 · 2012: 12
- FWCI
- 0.76
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Geologic Mapping
- Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Planetary Science and Exploration
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Keywords
- carbonate minerals, spectral reflectance, rhodochrosite, siderite, transition metal ions, ferrous iron, manganese(II), crystal field theory, mineral identification, near-infrared spectroscopy, visible spectroscopy
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
