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Rare-Earth distributions in the marine environment
Abstract
Analyses for the rare-earth elements in sea water, in a phosphorite, and in a manganese nodule were made by neutron activation and X-ray fluorescence techniques. These marine samples showed a depletion, in the heavier rare-earth elements, relative to chondritic meteorites, beginning with samarium. Cerium was enriched in the manganese nodule, probably as a result of its oxidation to the 4+ valence state. The ratios of the rare-earth abundances in the two minerals to those of sea water go through a maximum in the vicinity of samarium. The europium concentration, often anomalous in terrestrial minerals, was normal relative to the other rare earths in all of the samples. The sea water showed four times the concentration of rare earths at a depth of 4000 meters as compared with surface values.
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Citations
Cited by
Relative and Absolute Terrestrial Abundances of the Rare Earths
HASKIN, L. A., HASKIN, M. A., FREY, F. A., & WILDEMAN, T. R. (1968) · Origin and Distribution of the Elements · doi:10.1016/b978-0-08-012835-1.50074-x · Cited by 802
Rare earth elements in the Pacific and Atlantic Oceans
De Baar, H. J. W., Bacon, M. P., Brewer, P. G., & Bruland, K. W. (1985) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(85)90089-4 · Cited by 758
Rare earth element scavenging in seawater
Byrne, R. H., & Kim, K.-H. (1990) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(90)90002-3 · Cited by 549
Rare earth elements in the pore waters of reducing nearshore sediments
Elderfield, H., & Sholkovitz, E. R. (1987) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(87)90202-0 · Cited by 438
Redox cycling of rare earth elements in the suboxic zone of the Black Sea
German, C. R., Holliday, B. P., & Elderfield, H. (1991) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(91)90055-a · Cited by 371
Metadata
- Authors
- Goldberg, E. D., Koide, M., Schmitt, R. A., & Smith, R. H.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1963-07-15
- Volume
- 68
- Issue
- 14
- Pages
- 4209-4217
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2084027071
- Cited by
- 499
- References
- 0
- FWCI
- 10.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Rare-Earth distributions in the marine environment. https://app.cochat.ai/papers/10.1029/jz068i014p04209
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- Goldberg, E. D., Koide, M., Schmitt, R. A., & Smith, R. H. (1963). Rare-Earth distributions in the marine environment. Journal of Geophysical Research. https://doi.org/10.1029/jz068i014p04209
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.