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Measurement of the conductance of a hydrogen molecule
Open accessAbstract
Recent years have shown steady progress towards molecular electronics, in which molecules form basic components such as switches, diodes and electronic mixers. Often, a scanning tunnelling microscope is used to address an individual molecule, although this arrangement does not provide long-term stability. Therefore, metal–molecule–metal links using break-junction devices have also been explored; however, it is difficult to establish unambiguously that a single molecule forms the contact. Here we show that a single hydrogen molecule can form a stable bridge between platinum electrodes. In contrast to results for organic molecules, the bridge has a nearly perfect conductance of one quantum unit, carried by a single channel. The hydrogen bridge represents a simple test system in which to understand fundamental transport properties of single-molecule devices.
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Cites
Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
Cited by
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Joachim, C., & Ratner, M. A. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0500075102 · Cited by 522
Molecular junctions based on aromatic coupling
Wu, S., González, M. T., Huber, R., Grunder, S., Mayor, M., Schönenberger, C., & Calame, M. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.237 · Cited by 389
Metzger, R. M. (2015) · Chemical Reviews · doi:10.1021/cr500459d · Cited by 380
Nonlinear circuit foundations for nanodevices, part I: the four-element torus
Chua, L. O. (2003) · Proceedings of the IEEE · doi:10.1109/jproc.2003.818319 · Cited by 263
Iterative real-time path integral approach to nonequilibrium quantum transport
Weiss, S., Eckel, J., Thorwart, M., & Egger, R. (2008) · Physical Review B · doi:10.1103/physrevb.77.195316 · Cited by 211
Metadata
- Authors
- Smit, R. H. M., Noat, Y., Untiedt, C., Lang, N. D., van Hemert, M. C., & van Ruitenbeek, J. M.
- Venue
- Nature
- Published
- 2002-10-31
- Volume
- 419
- Issue
- 6910
- Pages
- 906-909
- ISSN
- 0028-0836 (ISSN-L)
- OpenAlex
- W1971622317
- Cited by
- 936
- References
- 1
- FWCI
- 46.27
- Type
- journal article
- Language
- en
- Open access
- green
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- Smit, R. H. M., Noat, Y., Untiedt, C., Lang, N. D., van Hemert, M. C., & van Ruitenbeek, J. M. (2002). Measurement of the conductance of a hydrogen molecule. Nature. https://doi.org/10.1038/nature01103
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