The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Covalent functionalization and passivation of exfoliated black phosphorus via aryl diazonium chemistry
Open accessAbstract
Functionalization of atomically thin nanomaterials enables the tailoring of their chemical, optical and electronic properties. Exfoliated black phosphorus (BP)-a layered two-dimensional semiconductor-exhibits favourable charge-carrier mobility, tunable bandgap and highly anisotropic properties, but it is chemically reactive and degrades rapidly in ambient conditions. Here we show that covalent aryl diazonium functionalization suppresses the chemical degradation of exfoliated BP even after three weeks of ambient exposure. This chemical modification scheme spontaneously forms phosphorus-carbon bonds, has a reaction rate sensitive to the aryl diazonium substituent and alters the electronic properties of exfoliated BP, ultimately yielding a strong, tunable p-type doping that simultaneously improves the field-effect transistor mobility and on/off current ratio. This chemical functionalization pathway controllably modifies the properties of exfoliated BP, and thus improves its prospects for nanoelectronic applications.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects
Piao, Y., Meany, B., Powell, L. R., Valley, N., Kwon, H., Schatz, G. C., & Wang, Y. (2013) · Nature Chemistry · doi:10.1038/nchem.1711 · Cited by 480
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Cited by
Light‐Induced Ambient Degradation of Few‐Layer Black Phosphorus: Mechanism and Protection
Zhou, Q., Chen, Q., Tong, Y., & Wang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605168 · Cited by 658
Zeng, X., Luo, M., Liu, G., Wang, X., Tao, W., Lin, Y., Ji, X., Nie, L., & Mei, L. (2018) · Advanced Science · doi:10.1002/advs.201800510 · Cited by 598
Black phosphorus nanostructures: recent advances in hybridization, doping and functionalization
Lei, W., Liu, G., Zhang, J., & Liu, M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00021a · Cited by 365
Recent Development of Aryl Diazonium Chemistry for the Derivatization of Aromatic Compounds
Mo, F., Qiu, D., Zhang, L., & Wang, J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01030 · Cited by 361
Electronic Transport in Two-Dimensional Materials
Sangwan, V. K., & Hersam, M. C. (2018) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-050317-021353 · Cited by 336
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Metadata
- Authors
- Ryder, C. R., Wood, J. D., Wells, S. A., Yang, Y., Jariwala, D., Marks, T. J., Schatz, G. C., & Hersam, M. C.
- Venue
- Nature Chemistry
- Published
- 2016-05-02
- Volume
- 8
- Issue
- 6
- Pages
- 597-602
- ISSN
- 1755-4330 (ISSN-L)
- 1755-4349
- OpenAlex
- W2345528437
- Cited by
- 822
- References
- 7
- FWCI
- 47.44
- Type
- journal article
- Language
- en
- Open access
- green
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