The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Metal–organic framework with optimally selective xenon adsorption and separation
Open accessAbstract
Nuclear energy is among the most viable alternatives to our current fossil fuel-based energy economy. The mass deployment of nuclear energy as a low-emissions source requires the reprocessing of used nuclear fuel to recover fissile materials and mitigate radioactive waste. A major concern with reprocessing used nuclear fuel is the release of volatile radionuclides such as xenon and krypton that evolve into reprocessing facility off-gas in parts per million concentrations. The existing technology to remove these radioactive noble gases is a costly cryogenic distillation; alternatively, porous materials such as metal–organic frameworks have demonstrated the ability to selectively adsorb xenon and krypton at ambient conditions. Here we carry out a high-throughput computational screening of large databases of metal–organic frameworks and identify SBMOF-1 as the most selective for xenon. We affirm this prediction and report that SBMOF-1 exhibits by far the highest reported xenon adsorption capacity and a remarkable Xe/Kr selectivity under conditions pertinent to nuclear fuel reprocessing.
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Cites
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Cited by
Chung, Y. G., Haldoupis, E., Bucior, B. J., Haranczyk, M., Lee, S., Zhang, H., Vogiatzis, K. D., Milisavljevic, M., Ling, S., Camp, J. S., et al. (2019) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.9b00835 · Cited by 863
Winarta, J., Shan, B., Mcintyre, S. M., Ye, L., Wang, C., Liu, J., & Mu, B. (2020) · Crystal Growth & Design · doi:10.1021/acs.cgd.9b00955 · Cited by 641
Self-citationSynthesis of novel nanomaterials and their application in efficient removal of radionuclides
Wang, X., Chen, L., Wang, L., Fan, Q., Pan, D., Li, J., Chi, F., Xie, Y., Yu, S., Xiao, C., et al. (2019) · Science China Chemistry · doi:10.1007/s11426-019-9492-4 · Cited by 365
Regeneration, degradation, and toxicity effect of MOFs: Opportunities and challenges
Kumar, P., Anand, B., Tsang, Y. F., Kim, K.-H., Khullar, S., & Wang, B. (2019) · Environmental Research · doi:10.1016/j.envres.2019.05.019 · Cited by 319
Present and future of MOF research in the field of adsorption and molecular separation
Petit, C. (2018) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2018.04.004 · Cited by 292
Metadata
- Authors
- Banerjee, D., Simon, C. M., Plonka, A. M., Motkuri, R. K., Liu, J., Chen, X., Smit, B., Parise, J. B., Haranczyk, M., & Thallapally, P. K.
- Venue
- Nature Communications
- Published
- 2016-06-13
- Volume
- 7
- Issue
- 1
- Pages
- ncomms11831-ncomms11831
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2430656774
- Cited by
- 466
- References
- 48
- FWCI
- 17.65
- Type
- journal article
- Language
- en
- Open access
- gold
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- Banerjee, D., Simon, C. M., Plonka, A. M., Motkuri, R. K., Liu, J., Chen, X., Smit, B., Parise, J. B., Haranczyk, M., & Thallapally, P. K. (2016). Metal–organic framework with optimally selective xenon adsorption and separation. Nature Communications. https://doi.org/10.1038/ncomms11831
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