The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis
Open accessAbstract
Despite intense research in past decades, the lack of high-performance catalysts for fuel cell reactions remains a challenge in realizing fuel cell technologies for transportation applications. Here we report a facile strategy for synthesizing hierarchical platinum-cobalt nanowires with high-index, platinum-rich facets and ordered intermetallic structure. These structural features enable unprecedented performance for the oxygen reduction and alcohol oxidation reactions. The specific/mass activities of the platinum-cobalt nanowires for oxygen reduction reaction are 39.6/33.7 times higher than commercial Pt/C catalyst, respectively. Density functional theory simulations reveal that the active threefold hollow sites on the platinum-rich high-index facets provide an additional factor in enhancing oxygen reduction reaction activities. The nanowires are stable in the electrochemical conditions and also thermally stable. This work may represent a key step towards scalable production of high-performance platinum-based nanowires for applications in catalysis and energy conversion.
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Metadata
- Authors
- Bu, L., Guo, S., Zhang, X., Shen, X., Su, D., Lu, G., Zhu, X., Yao, J., Guo, J., & Huang, X.
- Venue
- Nature Communications
- Published
- 2016-06-29
- Volume
- 7
- Issue
- 1
- Pages
- 11850-11850
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2471580804
- Cited by
- 737
- References
- 18
- FWCI
- 26.28
- Type
- journal article
- Language
- en
- Open access
- gold
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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