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Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance
Open accessAbstract
Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nanostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis. The graphene foam supported tin(II) sulfide nanoarray anode delivers a high reversible capacity of ∼1,100 mAh g−1 at 30 mA g−1 and ∼420 mAh g−1 at 30 A g−1, which even outperforms its lithium-ion storage performance. The surface-dominated redox reaction rendered by our tailored ultrathin tin(II) sulfide nanostructures may also work in other layered materials for high-performance sodium-ion storage.
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Where do batteries end and supercapacitors begin?
Simon, P., Gogotsi, Y., & Dunn, B. (2014) · Science · doi:10.1126/science.1249625 · Cited by 5,634
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Challenges and opportunities for supercapacitors
Huang, S., Zhu, X., Sarkar, S., & Zhao, Y. (2019) · APL Materials · doi:10.1063/1.5116146 · Cited by 533
Liu, Y., Yu, X.-Y., Fang, Y., Zhu, X., Bao, J., Zhou, X., & Lou, X. W. (. (2018) · Joule · doi:10.1016/j.joule.2018.01.004 · Cited by 359
Wang, T., Su, D., Shanmukaraj, D., Rojo, T., Armand, M., & Wang, G. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0009-9 · Cited by 328
Yang, J., Gao, H., Men, S., Shi, Z., Lin, Z., Kang, X., & Chen, S. (2018) · Advanced Science · doi:10.1002/advs.201800763 · Cited by 299
Engineering 2D Architectures toward High‐Performance Micro‐Supercapacitors
Da, Y., Liu, J., Zhou, L., Zhu, X., Chen, X., & Fu, L. (2019) · Advanced Materials · doi:10.1002/adma.201802793 · Cited by 253
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Metadata
- Authors
- Chao, D., Zhu, C., Yang, P., Xia, X., Liu, J., Wang, J., Fan, X., Savilov, S. V., Lin, J., Fan, H. J., & Shen, Z. X.
- Venue
- Nature Communications
- Published
- 2016-06-30
- Volume
- 7
- Issue
- 1
- Pages
- 12122-12122
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2463532845
- Cited by
- 1,447
- References
- 1
- FWCI
- 86.44
- Type
- journal article
- Language
- en
- Open access
- gold
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- Chao, D., Zhu, C., Yang, P., Xia, X., Liu, J., Wang, J., Fan, X., Savilov, S. V., Lin, J., Fan, H. J., & Shen, Z. X. (2016). Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance. Nature Communications. https://doi.org/10.1038/ncomms12122
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