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Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
Open accessAbstract
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalyst towards the catalytic nitrogen fixation, where a mixture of ammonia and hydrazine is produced. In the present reaction system, molecular dinitrogen is catalytically and directly converted into hydrazine by using transition metal-dinitrogen complexes as catalysts. Because hydrazine is considered as a key intermediate in the nitrogen fixation in nitrogenase, the findings described in this paper provide an opportunity to elucidate the reaction mechanism in nitrogenase.
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Self-citation
Metadata
- Authors
- Kuriyama, S., Arashiba, K., Nakajima, K., Matsuo, Y., Tanaka, H., Ishii, K., Yoshizawa, K., & Nishibayashi, Y.
- Venue
- Nature Communications
- Published
- 2016-07-20
- Volume
- 7
- Issue
- 1
- Pages
- 12181-12181
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2499262475
- Cited by
- 294
- References
- 33
- FWCI
- 19.60
- Type
- journal article
- Language
- en
- Open access
- gold
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