The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons
Open accessAbstract
Coupling vibrational transitions to resonant optical modes creates vibrational polaritons shifted from the uncoupled molecular resonances and provides a convenient way to modify the energetics of molecular vibrations. This approach is a viable method to explore controlling chemical reactivity. In this work, we report pump–probe infrared spectroscopy of the cavity-coupled C–O stretching band of W(CO)6 and the direct measurement of the lifetime of a vibration-cavity polariton. The upper polariton relaxes 10 times more quickly than the uncoupled vibrational mode. Tuning the polariton energy changes the polariton transient spectra and relaxation times. We also observe quantum beats, so-called vacuum Rabi oscillations, between the upper and lower vibration-cavity polaritons. In addition to establishing that coupling to an optical cavity modifies the energy-transfer dynamics of the coupled molecules, this work points out the possibility of systematic and predictive modification of the excited-state kinetics of vibration-cavity polariton systems.
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Cites
Polariton-Mediated Energy Transfer between Organic Dyes in a Strongly Coupled Optical Microcavity
Coles, D. M., Somaschi, N., Michetti, P., Clark, C., Lagoudakis, P. G., Savvidis, P. G., & Lidzey, D. G. (2014) · Nature Materials · doi:10.1038/nmat3950 · Cited by 507
Physics and Device Applications of Optical Microcavities
Yokoyama, H. (1992) · Science · doi:10.1126/science.256.5053.66 · Cited by 409
Toward control of electron transfer in donor-acceptor molecules by bond-specific infrared excitation
Delor, M., Scattergood, P. A., Sazanovich, I. V., Parker, A. W., Greetham, G. M., Meijer, A. J. H. M., Towrie, M., & Weinstein, J. A. (2014) · Science · doi:10.1126/science.1259995 · Cited by 199
Cited by
Novel Nanostructures and Materials for Strong Light–Matter Interactions
Baranov, D. G., Wersäll, M., Cuadra, J., Antosiewicz, T. J., & Shegai, T. (2018) · ACS Photonics · doi:10.1021/acsphotonics.7b00674 · Cited by 531
Strong light–matter interactions: a new direction within chemistry
Hertzog, M., Wang, M., Mony, J., & Börjesson, K. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00193f · Cited by 444
Metadata
- Authors
- Dunkelberger, A. D., Spann, B. T., Fears, K. P., Simpkins, B. S., & Owrutsky, J. C.
- Venue
- Nature Communications
- Published
- 2016-11-22
- Volume
- 7
- Issue
- 1
- Pages
- 13504-13504
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2551154894
- Cited by
- 216
- References
- 3
- FWCI
- 8.41
- Type
- journal article
- Language
- en
- Open access
- gold
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- Dunkelberger, A. D., Spann, B. T., Fears, K. P., Simpkins, B. S., & Owrutsky, J. C. (2016). Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons. Nature Communications. https://doi.org/10.1038/ncomms13504
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