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Metal/oxide interfacial effects on the selective oxidation of primary alcohols
Open accessAbstract
A main obstacle in the rational development of heterogeneous catalysts is the difficulty in identifying active sites. Here we show metal/oxide interfacial sites are highly active for the oxidation of benzyl alcohol and other industrially important primary alcohols on a range of metals and oxides combinations. Scanning tunnelling microscopy together with density functional theory calculations on FeO/Pt(111) reveals that benzyl alcohol enriches preferentially at the oxygen-terminated FeO/Pt(111) interface and undergoes readily O–H and C–H dissociations with the aid of interfacial oxygen, which is also validated in the model study of Cu 2 O/Ag(111). We demonstrate that the interfacial effects are independent of metal or oxide sizes and the way by which the interfaces were constructed. It inspires us to inversely support nano-oxides on micro-metals to make the structure more stable against sintering while the number of active sites is not sacrificed. The catalyst lifetime, by taking the inverse design, is thereby significantly prolonged.
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Cites
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
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Self-citationSingle‐Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis
Zhang, H., Liu, G., Shi, L., & Ye, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701343 · Cited by 1,078
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Wang, H., Gu, X.-K., Zheng, X., Pan, H., Zhu, J., Chen, S., Cao, L., Li, W.-X., & Lu, J. (2019) · Science Advances · doi:10.1126/sciadv.aat6413 · Cited by 408
Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts
Jiang, L., Liu, K., Hung, S.-F., Zhou, L., Qin, R., Zhang, Q., Liu, P., Gu, L., Chen, H. M., Fu, G., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-020-0746-x · Cited by 380
Metadata
- Authors
- Zhao, G., Yang, F., Chen, Z., Liu, Q., Ji, Y., Zhang, Y., Niu, Z., Mao, J., Bao, X., Hu, P., & Li, Y.
- Venue
- Nature Communications
- Published
- 2017-01-18
- Volume
- 8
- Issue
- 1
- Pages
- 14039-14039
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2579009013
- Cited by
- 211
- References
- 1
- FWCI
- 10.84
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhao, G., Yang, F., Chen, Z., Liu, Q., Ji, Y., Zhang, Y., Niu, Z., Mao, J., Bao, X., Hu, P., & Li, Y. (2017). Metal/oxide interfacial effects on the selective oxidation of primary alcohols. Nature Communications. https://doi.org/10.1038/ncomms14039
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