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Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials

Open access
Ding, Wenjun, Zhu, Jianbao, Wang, Zhe, Gao, Yanfei, Xiao, Di, Gu, Yi, Zhang, Zhenyu, Zhu, Wenguang·2017·Nature Communications

Abstract

Interest in two-dimensional (2D) van der Waals materials has grown rapidly across multiple scientific and engineering disciplines in recent years. However, ferroelectricity, the presence of a spontaneous electric polarization, which is important in many practical applications, has rarely been reported in such materials so far. Here we employ first-principles calculations to discover a branch of the 2D materials family, based on In 2 Se 3 and other III 2-VI 3 van der Waals materials, that exhibits room-temperature ferroelectricity with reversible spontaneous electric polarization in both out-of-plane and in-plane orientations. The device potential of these 2D ferroelectric materials is further demonstrated using the examples of van der Waals heterostructures of In 2 Se 3/graphene, exhibiting a tunable Schottky barrier, and In 2 Se 3/WSe 2, showing a significant band gap reduction in the combined system. These findings promise to substantially broaden the tunability of van der Waals heterostructures for a wide range of applications.

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Metadata

Authors
Ding, W., Zhu, J., Wang, Z., Gao, Y., Xiao, D., Gu, Y., Zhang, Z., & Zhu, W.
Venue
Nature Communications
Published
2017-04-07
Volume
8
Issue
1
Pages
14956-14956
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2605317103
Cited by
1,444
References
6
FWCI
27.10
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials. https://app.cochat.ai/papers/10.1038/ncomms14956
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Ding, W., Zhu, J., Wang, Z., Gao, Y., Xiao, D., Gu, Y., Zhang, Z., & Zhu, W. (2017). Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials. Nature Communications. https://doi.org/10.1038/ncomms14956

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