The DOI matches its Crossref record; 63 of the 63 references it cites were found in a registry or an index.
Understanding nanocellulose chirality and structure–properties relationship at the single fibril level
Open accessAbstract
Nanocellulose fibrils are ubiquitous in nature and nanotechnologies but their mesoscopic structural assembly is not yet fully understood. Here we study the structural features of rod-like cellulose nanoparticles on a single particle level, by applying statistical polymer physics concepts on electron and atomic force microscopy images, and we assess their physical properties via quantitative nanomechanical mapping. We show evidence of right-handed chirality, observed on both bundles and on single fibrils. Statistical analysis of contours from microscopy images shows a non-Gaussian kink angle distribution. This is inconsistent with a structure consisting of alternating amorphous and crystalline domains along the contour and supports process-induced kink formation. The intrinsic mechanical properties of nanocellulose are extracted from nanoindentation and persistence length method for transversal and longitudinal directions, respectively. The structural analysis is pushed to the level of single cellulose polymer chains, and their smallest associated unit with a proposed 2 × 2 chain-packing arrangement.
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Current characterization methods for cellulose nanomaterials
Foster, E. J., Moon, R. J., Agarwal, U. P., Bortner, M. J., Bras, J., Camarero-Espinosa, S., Chan, K. J., Clift, M. J. D., Cranston, E. D., Eichhorn, S. J., et al. (2018) · Chemical Society Reviews · doi:10.1039/c6cs00895j · Cited by 1,021
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Molecular insights into the complex mechanics of plant epidermal cell walls
Zhang, Y., Yu, J., Wang, X., Durachko, D. M., Zhang, S., & Cosgrove, D. J. (2021) · Science · doi:10.1126/science.abf2824 · Cited by 341
Molecular-level driving forces in lignocellulosic biomass deconstruction for bioenergy
Petridis, L., & Smith, J. C. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0050-6 · Cited by 228
Metadata
- Authors
- Usov, I., Nyström, G., Adamcik, J., Handschin, S., Schütz, C., Fall, A., Bergström, L., & Mezzenga, R.
- Venue
- Nature Communications
- Published
- 2015-06-25
- Volume
- 6
- Issue
- 1
- Pages
- 7564-7564
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W1678917879
- Cited by
- 498
- References
- 63
- FWCI
- 14.18
- Type
- journal article
- Language
- en
- Open access
- gold
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- Usov, I., Nyström, G., Adamcik, J., Handschin, S., Schütz, C., Fall, A., Bergström, L., & Mezzenga, R. (2015). Understanding nanocellulose chirality and structure–properties relationship at the single fibril level. Nature Communications. https://doi.org/10.1038/ncomms8564
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