The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production
Open accessAbstract
WSe 2—a layered semiconductor that can be exfoliated into atomically thin two-dimensional sheets—offers promising characteristics for application in solar energy conversion. However, the lack of controllable, cost-effective methods to scalably fabricate homogeneous thin films currently limits practical application. Here we present a technique to prepare controlled thin films of 2D WSe 2 from dispersions of solvent-exfoliated few-layer flakes. Flake self-assembly at a liquid/liquid interface (formed exceptionally from two non-solvents for WSe 2) followed by substrate transfer affords large-area thin films with superior 2D flake alignment compared with traditional (liquid/air) self-assembly techniques. We further demonstrate, for the first time, solar-to-hydrogen conversion from solution-processed WSe 2 thin films. Bare photoelectrodes with a thickness of ca. 25 nm exhibit sustained p-type photocurrent under simulated solar illumination, and up to 1.0 mA cm–2 at 0 V versus reversible hydrogen electrode with an added water reduction catalyst (Pt). The importance of the self-assembled morphology is established by photoelectrochemical and conductivity measurements.
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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
Atomically Thin MoS 2 : A New Direct-Gap Semiconductor
Mak, K. F., Lee, C., Hone, J., Shan, J., & Heinz, T. F. (2010) · Physical Review Letters · doi:10.1103/physrevlett.105.136805 · Cited by 15,586
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Liquid Exfoliation of Layered Materials
Nicolosi, V., Chhowalla, M., Kanatzidis, M. G., Strano, M. S., & Coleman, J. N. (2013) · Science · doi:10.1126/science.1226419 · Cited by 3,796
Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films
Britnell, L., Ribeiro, R. M., Eckmann, A., Jalil, R., Belle, B. D., Mishchenko, A., Kim, Y.-J., Gorbachev, R. V., Georgiou, T., Morozov, S. V., et al. (2013) · Science · doi:10.1126/science.1235547 · Cited by 2,581
Atomically thin p–n junctions with van der Waals heterointerfaces
Lee, C.-H., Lee, G.-H., van der Zande, A. M., Chen, W., Li, Y., Han, M., Cui, X., Arefe, G., Nuckolls, C., Heinz, T. F., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.150 · Cited by 2,303
Conducting MoS 2 Nanosheets as Catalysts for Hydrogen Evolution Reaction
Voiry, D., Salehi, M., Silva, R., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., & Chhowalla, M. (2013) · Nano Letters · doi:10.1021/nl403661s · Cited by 2,203
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting
Osterloh, F. E. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35266d · Cited by 2,047
Bernardi, M., Palummo, M., & Grossman, J. C. (2013) · Nano Letters · doi:10.1021/nl401544y · Cited by 2,043
Growth of Large-Area and Highly Crystalline MoS2 Thin Layers on Insulating Substrates
Liu, K.-K., Zhang, W., Lee, Y.-H., Lin, Y.-C., Chang, M.-T., Su, C.-Y., Chang, C.-S., Li, H., Shi, Y., Zhang, H., et al. (2012) · Nano Letters · doi:10.1021/nl2043612 · Cited by 1,958
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Recent Advances in Two-Dimensional Materials beyond Graphene
Bhimanapati, G. R., Lin, Z., Meunier, V., Jung, Y., Cha, J., Das, S., Xiao, D., Son, Y., Strano, M. S., Cooper, V. R., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b05556 · Cited by 2,659
Semiconducting materials for photoelectrochemical energy conversion
Sivula, K., & van de Krol, R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.10 · Cited by 1,645
Self-citationYang, W., Prabhakar, R. R., Tan, J., Tilley, S. D., & Moon, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00997j · Cited by 787
Li, C., Cao, Q., Wang, F., Xiao, Y., Li, Y., Delaunay, J.-J., & Zhu, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00067k · Cited by 494
Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis
Babu, G., Masurkar, N., Al Salem, H., & Arava, L. M. R. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08681 · Cited by 386
Novel structured transition metal dichalcogenide nanosheets
Zhang, X., Lai, Z., Ma, Q., & Zhang, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00094h · Cited by 386
Zhang, Z., Niu, J., Yang, P., Gong, Y., Ji, Q., Shi, J., Fang, Q., Jiang, S., Li, H., Zhou, X., et al. (2017) · Advanced Materials · doi:10.1002/adma.201702359 · Cited by 258
Metadata
- Authors
- Yu, X., Prévot, M. S., Guijarro, N., & Sivula, K.
- Venue
- Nature Communications
- Published
- 2015-07-01
- Volume
- 6
- Issue
- 1
- Pages
- 7596-7596
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W1526026297
- Cited by
- 278
- References
- 34
- FWCI
- 12.12
- Type
- journal article
- Language
- en
- Open access
- gold
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