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Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies
Open accessAbstract
Covalent organic frameworks (COFs) are an emerging class of highly ordered porous polymers with many potential applications. They are currently designed and synthesized through hexagonal and tetragonal topologies, limiting the access to and exploration of new structures and properties. Here, we report that a triangular topology can be developed for the rational design and synthesis of a new class of COFs. The triangular topology features small pore sizes down to 12 Å, which is among the smallest pores for COFs reported to date, and high π-column densities of up to 0.25 nm−2, which exceeds those of supramolecular columnar π-arrays and other COF materials. These crystalline COFs facilitate π-cloud delocalization and are highly conductive, with a hole mobility that is among the highest reported for COFs and polygraphitic ensembles.
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Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
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Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Machine Learning‐Assisted Design of Nitrogen‐Rich Covalent Triazine Frameworks Photocatalysts
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Metadata
- Authors
- Dalapati, S., Addicoat, M., Jin, S., Sakurai, T., Gao, J., Xu, H., Irle, S., Seki, S., & Jiang, D.
- Venue
- Nature Communications
- Published
- 2015-07-16
- Volume
- 6
- Issue
- 1
- Pages
- 7786-7786
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2252538303
- Cited by
- 366
- References
- 0
- FWCI
- 11.72
- Type
- journal article
- Language
- en
- Open access
- gold
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- Dalapati, S., Addicoat, M., Jin, S., Sakurai, T., Gao, J., Xu, H., Irle, S., Seki, S., & Jiang, D. (2015). Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies. Nature Communications. https://doi.org/10.1038/ncomms8786
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