The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics
Open accessAbstract
Few-layer black phosphorus (BP) is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of environmental stability severely limits its synthesis and processing. Here we demonstrate that high-quality, few-layer BP nanosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase exfoliation under ambient conditions in solvents such as N-cyclohexyl-2-pyrrolidone (CHP). Nanosheets are surprisingly stable in CHP, probably due to the solvation shell protecting the nanosheets from reacting with water or oxygen. Experiments, supported by simulations, show reactions to occur only at the nanosheet edge, with the rate and extent of the reaction dependent on the water/oxygen content. We demonstrate that liquid-exfoliated BP nanosheets are potentially useful in a range of applications from ultrafast saturable absorbers to gas sensors to fillers for composite reinforcement.
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Cites
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., & Strano, M. S. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.193 · Cited by 16,374
Self-citationGraphene: Status and Prospects
Geim, A. K. (2009) · Science · doi:10.1126/science.1158877 · Cited by 13,942
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Cited by
Recent development of two-dimensional transition metal dichalcogenides and their applications
Choi, W., Choudhary, N., Han, G. H., Park, J., Akinwande, D., & Lee, Y. H. (2017) · Materials Today · doi:10.1016/j.mattod.2016.10.002 · Cited by 2,769
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Zeng, M., Xiao, Y., Liu, J., Yang, K., & Fu, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00633 · Cited by 574
Interaction of Black Phosphorus with Oxygen and Water
Huang, Y., Qiao, J., He, K., Bliznakov, S., Sutter, E., Chen, X., Luo, D., Meng, F., Su, D., Decker, J., et al. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b03592 · Cited by 532
Metadata
- Authors
- Hanlon, D., Backes, C., Doherty, E., Cucinotta, C. S., Berner, N. C., Boland, C., Lee, K., Harvey, A., Lynch, P., Gholamvand, Z., Zhang, S., Wang, K., Moynihan, G., Pokle, A., Ramasse, Q. M., McEvoy, N., Blau, W. J., Wang, J., Abellan, G., Hauke, F., Hirsch, A., Sanvito, S., O’Regan, D. D., Duesberg, G. S., Nicolosi, V., & Coleman, J. N.
- Venue
- Nature Communications
- Published
- 2015-10-15
- Volume
- 6
- Issue
- 1
- Pages
- 8563-8563
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W1603084134
- Cited by
- 1,104
- References
- 4
- FWCI
- 48.76
- Type
- journal article
- Language
- en
- Open access
- gold
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