The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Template-free nanosized faujasite-type zeolites
Abstract
Nanosized faujasite (FAU) crystals have great potential as catalysts or adsorbents to more efficiently process present and forthcoming synthetic and renewable feedstocks in oil refining, petrochemistry and fine chemistry. Here, we report the rational design of template-free nanosized FAU zeolites with exceptional properties, including extremely small crystallites (10-15 nm) with a narrow particle size distribution, high crystalline yields (above 80%), micropore volumes (0.30 cm(3) g(-1)) comparable to their conventional counterparts (micrometre-sized crystals), Si/Al ratios adjustable between 1.1 and 2.1 (zeolites X or Y) and excellent thermal stability leading to superior catalytic performance in the dealkylation of a bulky molecule, 1,3,5-triisopropylbenzene, probing sites mostly located on the external surface of the nanosized crystals. Another important feature is their excellent colloidal stability, which facilitates a uniform dispersion on supports for applications in catalysis, sorption and thin-to-thick coatings.
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“The reduction of average crystal size of a zeolite is mostly done directly by hydrothermal synthesis promoting nucleation versus crystal growth,99,134−138 although other nonconventional methods have been applied as well.139”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [135]
Citations
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Sun, M., Huang, S., Chen, L., Li, Y., Yang, X., Yuan, Z., & Su, B. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00135a · Cited by 1,462
Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons
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Metadata
- Authors
- Awala, H., Gilson, J.-P., Retoux, R., Boullay, P., Goupil, J.-M., Valtchev, V., & Mintova, S.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Mintova, Svetlana
- Venue
- Nature Materials
- Published
- 2015-01-05
- Volume
- 14
- Issue
- 4
- Pages
- 447-451
- ISSN
- 1476-1122 (ISSN-L)
- 1476-4660
- OpenAlex
- W1994047443
- Cited by
- 484
- References
- 39
- Citations by year
- 2026: 20 · 2025: 41 · 2024: 51 · 2023: 42 · 2022: 40 · 2021: 45 · 2020: 56 · 2019: 40 · 2018: 50 · 2017: 42 · 2016: 38 · 2015: 19
- FWCI
- 20.40
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nature Materials (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- faujasite, nanosized zeolites, template-free synthesis, zeolite crystallization, Si/Al ratio, zeolite X, zeolite Y, thermal stability, dealkylation, 1,3,5-triisopropylbenzene, colloidal stability, particle size distribution, catalysts, adsorbents
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