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Alkaline earth metal vanadates as sodium-ion battery anodes

Open access
Xu, Xiaoming, Niu, Chaojiang, Duan, Manyi, Wang, Xuanpeng, Huang, Lei, Wang, Junhui, Pu, Liting, Ren, Wenhao, Shi, Changwei, Meng, Jiasheng, Song, Bo, Mai, Liqiang·2017·Nature Communications

Abstract

The abundance of sodium resources indicates the potential of sodium-ion batteries as emerging energy storage devices. However, the practical application of sodium-ion batteries is hindered by the limited electrochemical performance of electrode materials, especially at the anode side. Here, we identify alkaline earth metal vanadates as promising anodes for sodium-ion batteries. The prepared calcium vanadate nanowires possess intrinsically high electronic conductivity (> 100 S cm−1), small volume change (< 10%), and a self-preserving effect, which results in a superior cycling and rate performance and an applicable reversible capacity (> 300 mAh g−1), with an average voltage of ∼1.0 V. The specific sodium-storage mechanism, beyond the conventional intercalation or conversion reaction, is demonstrated through in situ and ex situ characterizations and theoretical calculations. This work explores alkaline earth metal vanadates for sodium-ion battery anodes and may open a direction for energy storage.

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Metadata

Authors
Xu, X., Niu, C., Duan, M., Wang, X., Huang, L., Wang, J., Pu, L., Ren, W., Shi, C., Meng, J., Song, B., & Mai, L.
Venue
Nature Communications
Published
2017-09-06
Volume
8
Issue
1
Pages
460-460
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2752453931
Cited by
163
References
0
FWCI
8.06
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Alkaline earth metal vanadates as sodium-ion battery anodes. https://app.cochat.ai/papers/10.1038/s41467-017-00211-5
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Xu, X., Niu, C., Duan, M., Wang, X., Huang, L., Wang, J., Pu, L., Ren, W., Shi, C., Meng, J., Song, B., & Mai, L. (2017). Alkaline earth metal vanadates as sodium-ion battery anodes. Nature Communications. https://doi.org/10.1038/s41467-017-00211-5

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