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Alkaline earth metal vanadates as sodium-ion battery anodes
Open accessAbstract
The abundance of sodium resources indicates the potential of sodium-ion batteries as emerging energy storage devices. However, the practical application of sodium-ion batteries is hindered by the limited electrochemical performance of electrode materials, especially at the anode side. Here, we identify alkaline earth metal vanadates as promising anodes for sodium-ion batteries. The prepared calcium vanadate nanowires possess intrinsically high electronic conductivity (> 100 S cm−1), small volume change (< 10%), and a self-preserving effect, which results in a superior cycling and rate performance and an applicable reversible capacity (> 300 mAh g−1), with an average voltage of ∼1.0 V. The specific sodium-storage mechanism, beyond the conventional intercalation or conversion reaction, is demonstrated through in situ and ex situ characterizations and theoretical calculations. This work explores alkaline earth metal vanadates for sodium-ion battery anodes and may open a direction for energy storage.
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Cited by
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
Xu, X., Xiong, F., Meng, J., Wang, X., Niu, C., An, Q., & Mai, L. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201904398 · Cited by 482
Self-citationNanowires for Electrochemical Energy Storage
Zhou, G., Xu, L., Hu, G., Mai, L., & Cui, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00326 · Cited by 439
Self-citationWang, T., Su, D., Shanmukaraj, D., Rojo, T., Armand, M., & Wang, G. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0009-9 · Cited by 328
Sun, Y., Guo, S., & Zhou, H. (2019) · Energy & Environmental Science · doi:10.1039/c8ee01006d · Cited by 322
Metadata
- Authors
- Xu, X., Niu, C., Duan, M., Wang, X., Huang, L., Wang, J., Pu, L., Ren, W., Shi, C., Meng, J., Song, B., & Mai, L.
- Venue
- Nature Communications
- Published
- 2017-09-06
- Volume
- 8
- Issue
- 1
- Pages
- 460-460
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2752453931
- Cited by
- 163
- References
- 0
- FWCI
- 8.06
- Type
- journal article
- Language
- en
- Open access
- gold
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- Xu, X., Niu, C., Duan, M., Wang, X., Huang, L., Wang, J., Pu, L., Ren, W., Shi, C., Meng, J., Song, B., & Mai, L. (2017). Alkaline earth metal vanadates as sodium-ion battery anodes. Nature Communications. https://doi.org/10.1038/s41467-017-00211-5
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