The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries
Open accessAbstract
Magnesium rechargeable batteries potentially offer high-energy density, safety, and low cost due to the ability to employ divalent, dendrite-free, and earth-abundant magnesium metal anode. Despite recent progress, further development remains stagnated mainly due to the sluggish scission of magnesium-chloride bond and slow diffusion of divalent magnesium cations in cathodes. Here we report a battery chemistry that utilizes magnesium monochloride cations in expanded titanium disulfide. Combined theoretical modeling, spectroscopic analysis, and electrochemical study reveal fast diffusion kinetics of magnesium monochloride cations without scission of magnesium-chloride bond. The battery demonstrates the reversible intercalation of 1 and 1.7 magnesium monochloride cations per titanium at 25 and 60 °C, respectively, corresponding to up to 400 mAh g−1 capacity based on the mass of titanium disulfide. The large capacity accompanies with excellent rate and cycling performances even at room temperature, opening up possibilities for a variety of effective intercalation hosts for multivalent-ion batteries.
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Cited by
Tian, Y., Zeng, G., Rutt, A., Shi, T., Kim, H., Wang, J., Koettgen, J., Sun, Y., Ouyang, B., Chen, T., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00767 · Cited by 1,614
Yang, J., Ju, Z., Jiang, Y., Xing, Z., Xi, B., Feng, J., & Xiong, S. (2018) · Advanced Materials · doi:10.1002/adma.201700104 · Cited by 849
Greim, P., Solomon, A. A., & Breyer, C. (2020) · Nature Communications · doi:10.1038/s41467-020-18402-y · Cited by 554
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
Xu, X., Xiong, F., Meng, J., Wang, X., Niu, C., An, Q., & Mai, L. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201904398 · Cited by 482
Self-citationStructural Engineering of 2D Nanomaterials for Energy Storage and Catalysis
Zhu, Y., Peng, L., Fang, Z., Yan, C., Zhang, X., & Yu, G. (2018) · Advanced Materials · doi:10.1002/adma.201706347 · Cited by 451
Metadata
- Authors
- Yoo, H. D., Liang, Y., Dong, H., Lin, J., Wang, H., Liu, Y., Ma, L., Wu, T., Li, Y., Ru, Q., Jing, Y., An, Q., Zhou, W., Guo, J., Lu, J., Pantelides, S. T., Qian, X., & Yao, Y.
- Venue
- Nature Communications
- Published
- 2017-08-24
- Volume
- 8
- Issue
- 1
- Pages
- 339-339
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2745716590
- Cited by
- 396
- References
- 49
- FWCI
- 17.45
- Type
- journal article
- Language
- en
- Open access
- gold
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- Yoo, H. D., Liang, Y., Dong, H., Lin, J., Wang, H., Liu, Y., Ma, L., Wu, T., Li, Y., Ru, Q., Jing, Y., An, Q., Zhou, W., Guo, J., Lu, J., Pantelides, S. T., Qian, X., & Yao, Y. (2017). Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries. Nature Communications. https://doi.org/10.1038/s41467-017-00431-9
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