The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides
Open accessAbstract
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at high potentials, thereby promising high energy densities for lithium-ion batteries. However, anion redox is also associated with several unfavorable electrochemical properties, such as open-circuit voltage hysteresis. Here we reveal that in Li 1.17–x Ni 0.21 Co 0.08 Mn 0.54 O 2, these properties arise from a strong coupling between anion redox and cation migration. We combine various X-ray spectroscopic, microscopic, and structural probes to show that partially reversible transition metal migration decreases the potential of the bulk oxygen redox couple by > 1 V, leading to a reordering in the anionic and cationic redox potentials during cycling. First principles calculations show that this is due to the drastic change in the local oxygen coordination environments associated with the transition metal migration. We propose that this mechanism is involved in stabilizing the oxygen redox couple, which we observe spectroscopically to persist for 500 charge/discharge cycles.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
Giannozzi, P., Baroni, S., Bonini, N., Calandra, M., Car, R., Cavazzoni, C., Ceresoli, D., Chiarotti, G. L., Cococcioni, M., Dabo, I., et al. (2009) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/21/39/395502 · Cited by 29,281
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
ATHENA,ARTEMIS,HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT
Ravel, B., & Newville, M. (2005) · Journal of Synchrotron Radiation · doi:10.1107/s0909049505012719 · Cited by 16,965
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
Dudarev, S. L., Botton, G. A., Savrasov, S. Y., Humphreys, C. J., & Sutton, A. P. (1998) · Physical Review B · doi:10.1103/physrevb.57.1505 · Cited by 15,173
Relations between the Concentrations of Imperfections in Crystalline Solids
Kröger, F. A., & Vink, H. J. (1956) · Solid State Physics · doi:10.1016/s0081-1947(08)60135-6 · Cited by 2,125
Cited by
Huang, Z.-F., Song, J., Du, Y., Xi, S., Dou, S., Nsanzimana, J. M. V., Wang, C., Xu, Z. J., & Wang, X. (2019) · Nature Energy · doi:10.1038/s41560-019-0355-9 · Cited by 1,858
Self-citationSuperstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes
House, R. A., Maitra, U., Pérez-Osorio, M. A., Lozano, J. G., Jin, L., Somerville, J. W., Duda, L. C., Nag, A., Walters, A., Zhou, K.-J., et al. (2020) · Nature · doi:10.1038/s41586-019-1854-3 · Cited by 848
Clément, R. J., Lun, Z., & Ceder, G. (2020) · Energy & Environmental Science · doi:10.1039/c9ee02803j · Cited by 560
Zuo, W., Luo, M., Liu, X., Wu, J., Liu, H., Li, J., Winter, M., Fu, R., Yang, W., & Yang, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01694b · Cited by 429
Self-citationLi, Q., Wang, Y., Wang, X., Sun, X., Zhang, J.-N., Yu, X., & Li, H. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b16727 · Cited by 319
Self-citation
Metadata
- Authors
- Gent, W. E., Lim, K., Liang, Y., Li, Q., Barnes, T., Ahn, S.-J., Stone, K. H., McIntire, M., Hong, J., Song, J. H., Li, Y., Mehta, A., Ermon, S., Tyliszczak, T., Kilcoyne, D., Vine, D., Park, J.-H., Doo, S.-K., Toney, M. F., Yang, W., Prendergast, D., & Chueh, W. C.
- Venue
- Nature Communications
- Published
- 2017-12-12
- Volume
- 8
- Issue
- 1
- Pages
- 2091-2091
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2771526032
- Cited by
- 695
- References
- 53
- FWCI
- 20.81
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides. https://app.cochat.ai/papers/10.1038/s41467-017-02041-x
- The paper
- Gent, W. E., Lim, K., Liang, Y., Li, Q., Barnes, T., Ahn, S.-J., Stone, K. H., McIntire, M., Hong, J., Song, J. H., Li, Y., Mehta, A., Ermon, S., Tyliszczak, T., Kilcoyne, D., Vine, D., Park, J.-H., Doo, S.-K., Toney, M. F., . . . Chueh, W. C. (2017). Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides. Nature Communications. https://doi.org/10.1038/s41467-017-02041-x
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
