The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Anion insertion enhanced electrodeposition of robust metal hydroxide/oxide electrodes for oxygen evolution
Open accessAbstract
Electrochemical deposition is a facile strategy to prepare functional materials but suffers from limitation in thin films and uncontrollable interface engineering. Here we report a universal electrosynthesis of metal hydroxides/oxides on varied substrates via reduction of oxyacid anions. On graphitic substrates, we find that the insertion of nitrate ion in graphene layers significantly enhances the electrodeposit–support interface, resulting in high mass loading and super hydrophilic/aerophobic properties. For the electrocatalytic oxygen evolution reaction, the nanocrystalline cerium dioxide and amorphous nickel hydroxide co-electrodeposited on graphite exhibits low overpotential (177 mV@10 mA cm−2) and sustains long-term durability (over 300 h) at a large current density of 1000 mA cm−2. In situ Raman and operando X-ray diffraction unravel that the integration of cerium promotes the formation of electrocatalytically active gamma-phase nickel oxyhydroxide with exposed (003) facets. Therefore, combining anion intercalation with cathodic electrodeposition allows building robust electrodes with high electrochemical performance.
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McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Homogeneously dispersed multimetal oxygen-evolving catalysts
Zhang, B., Zheng, X., Voznyy, O., Comin, R., Bajdich, M., García-Melchor, M., Han, L., Xu, J., Liu, M., Zheng, L., et al. (2016) · Science · doi:10.1126/science.aaf1525 · Cited by 2,447
Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride
Chen, G. Z., Fray, D. J., & Farthing, T. W. (2000) · Nature · doi:10.1038/35030069 · Cited by 1,537
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257
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Recent Advances in Design of Electrocatalysts for High‐Current‐Density Water Splitting
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Single atom tungsten doped ultrathin α-Ni(OH)2 for enhanced electrocatalytic water oxidation
Yan, J., Kong, L., Ji, Y., White, J., Li, Y., Zhang, J., An, P., Liu, S., Lee, S.-T., & Ma, T. (2019) · Nature Communications · doi:10.1038/s41467-019-09845-z · Cited by 561
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Metadata
- Authors
- Yan, Z., Sun, H., Chen, X., Liu, H., Zhao, Y., Li, H., Xie, W., Cheng, F., & Chen, J.
- Venue
- Nature Communications
- Published
- 2018-06-18
- Volume
- 9
- Issue
- 1
- Pages
- 2373-2373
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2808604530
- Cited by
- 573
- References
- 4
- FWCI
- 9.56
- Type
- journal article
- Language
- en
- Open access
- gold
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