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Overall water splitting by graphdiyne-exfoliated and -sandwiched layered double-hydroxide nanosheet arrays
Open accessAbstract
It is of great urgency to develop efficient, cost-effective, stable and industrially applicable electrocatalysts for renewable energy systems. But there are still few candidate materials. Here we show a bifunctional electrocatalyst, comprising graphdiyne-exfoliated and -sandwiched iron/cobalt layered double-hydroxide nanosheet arrays grown on nickel foam, for the oxygen and hydrogen evolution reactions. Theoretical and experimental data revealed that the charge transport kinetics of the structure were superior to iron/cobalt layered double-hydroxide, a prerequisite for improved electrocatalytic performance. The incorporation with graphdiyne increased the number of catalytically active sites and prevented corrosion, leading to greatly enhanced electrocatalytic activity and stability for oxygen evolution reaction, hydrogen evolution reaction, as well as overall water splitting. Our results suggest that the use of graphdiyne might open up new pathways for the design and fabrication of earth-abundant, efficient, functional, and smart electrode materials with practical applications.
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Cites
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Homogeneously dispersed multimetal oxygen-evolving catalysts
Zhang, B., Zheng, X., Voznyy, O., Comin, R., Bajdich, M., García-Melchor, M., Han, L., Xu, J., Liu, M., Zheng, L., et al. (2016) · Science · doi:10.1126/science.aaf1525 · Cited by 2,447
Self-citationJin, H., Wang, J., Su, D., Wei, Z., Pang, Z., & Wang, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5127165 · Cited by 1,765
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
Self-citationJia, X., Zhao, Y., Chen, G., Shang, L., Shi, R., Kang, X., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502585 · Cited by 773
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Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis
Yu, L., Zhu, Q., Song, S., McElhenny, B., Wang, D., Wu, C., Qin, Z., Bao, J., Yu, Y., Chen, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-13092-7 · Cited by 1,333
Yu, L., Wu, L., McElhenny, B., Song, S., Luo, D., Zhang, F., Yu, Y., Chen, S., & Ren, Z. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00921k · Cited by 877
2D graphdiyne: An emerging carbon material
Fang, Y., Liu, Y., Qi, L., Xue, Y., & Li, Y. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00592h · Cited by 520
Self-citationSelf-supported electrocatalysts for practical water electrolysis
Yang, H., Driess, M., & Menezes, P. W. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202102074 · Cited by 489
Chen, W., Gu, J., Du, Y., Song, F., Bu, F., Li, J., Yuan, Y., Luo, R., Liu, Q., & Zhang, D. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000551 · Cited by 117
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Metadata
- Authors
- Hui, L., Xue, Y., Huang, B., Yu, H., Zhang, C., Zhang, D., Jia, D., Zhao, Y., Li, Y., Liu, H., & Li, Y.
- Venue
- Nature Communications
- Published
- 2018-12-14
- Volume
- 9
- Issue
- 1
- Pages
- 5309-5309
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2904379531
- Cited by
- 377
- References
- 5
- FWCI
- 9.50
- Type
- journal article
- Language
- en
- Open access
- gold
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- Hui, L., Xue, Y., Huang, B., Yu, H., Zhang, C., Zhang, D., Jia, D., Zhao, Y., Li, Y., Liu, H., & Li, Y. (2018). Overall water splitting by graphdiyne-exfoliated and -sandwiched layered double-hydroxide nanosheet arrays. Nature Communications. https://doi.org/10.1038/s41467-018-07790-x
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