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Strain engineering in perovskite solar cells and its impacts on carrier dynamics

Open access
Zhu, Cheng, Niu, Xiuxiu, Fu, Yuhao, Li, Nengxu, Hu, Chen, Chen, Yihua, He, Xin, Na, Guangren, Liu, Pengfei, Zai, Huachao, Ge, Yang, Lu, Yue, Ke, Xiaoxing, Bai, Yang, Yang, Shihe, Chen, Pengwan, Li, Yujing, Sui, Manling, Zhang, Lijun, Zhou, Huanping, Chen, Qi·2019·Nature Communications

Abstract

The mixed halide perovskites have emerged as outstanding light absorbers for efficient solar cells. Unfortunately, it reveals inhomogeneity in these polycrystalline films due to composition separation, which leads to local lattice mismatches and emergent residual strains consequently. Thus far, the understanding of these residual strains and their effects on photovoltaic device performance is absent. Herein we study the evolution of residual strain over the films by depth-dependent grazing incident X-ray diffraction measurements. We identify the gradient distribution of in-plane strain component perpendicular to the substrate. Moreover, we reveal its impacts on the carrier dynamics over corresponding solar cells, which is stemmed from the strain induced energy bands bending of the perovskite absorber as indicated by first-principles calculations. Eventually, we modulate the status of residual strains in a controllable manner, which leads to enhanced PCEs up to 20.7% (certified) in devices via rational strain engineering.

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Metadata

Authors
Zhu, C., Niu, X., Fu, Y., Li, N., Hu, C., Chen, Y., He, X., Na, G., Liu, P., Zai, H., Ge, Y., Lu, Y., Ke, X., Bai, Y., Yang, S., Chen, P., Li, Y., Sui, M., Zhang, L., Zhou, H., & Chen, Q.
Venue
Nature Communications
Published
2019-02-18
Volume
10
Issue
1
Pages
815-815
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2912153941
Cited by
1,042
References
4
FWCI
32.43
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Strain engineering in perovskite solar cells and its impacts on carrier dynamics. https://app.cochat.ai/papers/10.1038/s41467-019-08507-4
The paper
Zhu, C., Niu, X., Fu, Y., Li, N., Hu, C., Chen, Y., He, X., Na, G., Liu, P., Zai, H., Ge, Y., Lu, Y., Ke, X., Bai, Y., Yang, S., Chen, P., Li, Y., Sui, M., Zhang, L., . . . Chen, Q. (2019). Strain engineering in perovskite solar cells and its impacts on carrier dynamics. Nature Communications. https://doi.org/10.1038/s41467-019-08507-4

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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