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Cited by 308

The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.

Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors

Open access
Li, Xiaojun, Pan, Fei, Sun, Chenkai, Zhang, Ming, Wang, Zhiwei, Du, Jiaqi, Wang, Jing, Xiao, Min, Xue, Lingwei, Zhang, Zhi-Guo, Zhang, Chunfeng, Liu, Feng, Li, Yongfang·2019·Nature Communications

Abstract

The application of polymer solar cells (PSCs) with n-type organic semiconductor as acceptor requires further improving powder conversion efficiency, increasing stability and decreasing cost of the related materials and devices. Here we report a simplified synthetic route for 4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno [1,2-b:5,6-b’] dithiophene by using the catalyst of amberlyst15. Based on this synthetic route and methoxy substitution, two low cost acceptors with less synthetic steps, simple post-treatment and high yield were synthesized. In addition, the methoxy substitution improves both yield and efficiency. The high efficiency of 13.46% was obtained for the devices with MO-IDIC-2F (3,9-bis(2-methylene-5 or 6-fluoro-(3-(1,1-dicyanomethylene)-indanone)-4,4,9,9-tetrahexyl-5,10-dimethoxyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b’] dithiophene) as acceptor. Based on the cost analysis, the PSCs based on MO-IDIC-2F possess the great advantages of low cost and high photovoltaic performance in comparison with those PSCs reported in literatures. Therefore, MO-IDIC-2F will be a promising low cost acceptor for commercial application of PSCs.

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Metadata

Authors
Li, X., Pan, F., Sun, C., Zhang, M., Wang, Z., Du, J., Wang, J., Xiao, M., Xue, L., Zhang, Z.-G., Zhang, C., Liu, F., & Li, Y.
Venue
Nature Communications
Published
2019-01-31
Volume
10
Issue
1
Pages
519-519
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2911579890
Cited by
308
References
51
FWCI
16.57
Type
journal article
Language
en
Open access
gold

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Li, X., Pan, F., Sun, C., Zhang, M., Wang, Z., Du, J., Wang, J., Xiao, M., Xue, L., Zhang, Z.-G., Zhang, C., Liu, F., & Li, Y. (2019). Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors. Nature Communications. https://doi.org/10.1038/s41467-019-08508-3

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