The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.
Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors
Open accessAbstract
The application of polymer solar cells (PSCs) with n-type organic semiconductor as acceptor requires further improving powder conversion efficiency, increasing stability and decreasing cost of the related materials and devices. Here we report a simplified synthetic route for 4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno [1,2-b:5,6-b’] dithiophene by using the catalyst of amberlyst15. Based on this synthetic route and methoxy substitution, two low cost acceptors with less synthetic steps, simple post-treatment and high yield were synthesized. In addition, the methoxy substitution improves both yield and efficiency. The high efficiency of 13.46% was obtained for the devices with MO-IDIC-2F (3,9-bis(2-methylene-5 or 6-fluoro-(3-(1,1-dicyanomethylene)-indanone)-4,4,9,9-tetrahexyl-5,10-dimethoxyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b’] dithiophene) as acceptor. Based on the cost analysis, the PSCs based on MO-IDIC-2F possess the great advantages of low cost and high photovoltaic performance in comparison with those PSCs reported in literatures. Therefore, MO-IDIC-2F will be a promising low cost acceptor for commercial application of PSCs.
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Self-citationEnhanced power-conversion efficiency in polymer solar cells using an inverted device structure
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Cited by
Renewed Prospects for Organic Photovoltaics
Zhang, G., Lin, F. R., Qi, F., Heumüller, T., Distler, A., Egelhaaf, H.-J., Li, N., Chow, P. C. Y., Brabec, C. J., Jen, A. K.-Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00955 · Cited by 1,052
Metadata
- Authors
- Li, X., Pan, F., Sun, C., Zhang, M., Wang, Z., Du, J., Wang, J., Xiao, M., Xue, L., Zhang, Z.-G., Zhang, C., Liu, F., & Li, Y.
- Venue
- Nature Communications
- Published
- 2019-01-31
- Volume
- 10
- Issue
- 1
- Pages
- 519-519
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2911579890
- Cited by
- 308
- References
- 51
- FWCI
- 16.57
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, X., Pan, F., Sun, C., Zhang, M., Wang, Z., Du, J., Wang, J., Xiao, M., Xue, L., Zhang, Z.-G., Zhang, C., Liu, F., & Li, Y. (2019). Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors. Nature Communications. https://doi.org/10.1038/s41467-019-08508-3
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